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Materials and Coatings
Phase Transformation Strengthened Disk Alloy for Commercial Application
TSNA-C is a nickel-based disk alloy designed around the familiar gamma/gamma-prime superalloy microstructure, but augmented by local phase transformation (LPT) strengthening that activates under creep. During high-temperature service, specific superlattice stacking faults become sites for controlled atomic-scale transformations, which harden those faults, suppress shear pathways (including microtwinning), and slow the mechanisms that typically degrade lifespan due to creep. This fault-level reinforcement is paired with a commercial-ready composition window tuned to balance transformation strengthening with forgeability and heat-treat response, enabling integration into powder-metallurgy routes such as Hot Isostatic Pressing, forging, and standard thermal processing. In NASA development, TSNA alloys formed the expected gamma/gamma-prime microstructure and preliminary tensile and fatigue-crack-growth evaluations at elevated temperature were within acceptable ranges for disk materials. Additionally, phase-stability checks after long-duration exposures showed no deleterious topologically close-packed (TCP) phase formation. Together, properties provide a disk alloy that can sustain higher hot-section demands with a balanced property profile, while fitting the workflows and cost expectations familiar to engine OEMs and suppliers. Forged variants demonstrated markedly improved high-temperature creep behavior, motivating a commercial composition that balances processability with fault-level strengthening. This technology is assessed at a Technology Readiness Level (TRL) 5 and is available for patent licensing.
materials and coatings
High-Temperature Ni-Based Superalloy Composition
NASA's new Ni-based superalloy uses a powder metallurgy (PM) composition that inhibits the deleterious gamma-prime to gamma-phase transformation along stacking faults during high temperature creep deformation. Ni-base superalloys have excellent high temperature properties, mostly due to the presence of coherent precipitates. At higher temperatures, these precipitates are defeated by the diffusional shear dislocations producing intrinsic and extrinsic faults. Recent studies have found that, during deformation of turbine disk alloys at high temperature, Co, Cr, and Mo segregate to these faults (removing Ni and Al) inside the strengthening precipitates of these alloys. This represents a local phase transformation from the strengthening precipitate to the weaker matrix phase. Therefore, this elemental segregation significantly weakens the ability of a precipitate to withstand further deformation, producing faster strain rates in the alloy at higher temperatures. This invention presents a solution to prevent this type of segregation along these two faults to improve the creep properties of turbine disks and similar Ni-based alloys. By alloying a specific amount of eta phase formers (Ti, Ta, Nb, and Hf), the phase transformation to can be eliminated along 2-layer extrinsic stacking faults (SESFs) in precipitates without precipitating bulk eta phase. Also, by adding a certain amount of D019 formers (Mo and W), the phase transformation to can be mitigated along 1-layer intrinsic stacking faults (SISFs) without producing bulk sigma phase. This alloy composition incorporates both strengthening methods for use in jet turbine disks, though the composition has applications in other high-stress and/or high-temperature environments as are found in power plants, space launch systems, and other critical structural applications.
Materials and Coatings
Laser powder bed fusion manufactured tensile rods for tensile testing of GRC103y. Credit: NASA
GRC103y: Nano-Yttria Strengthened C103 for Additive Manufacturing
The manufacturing process, building on techniques showcased in LEW-TOPS-151, employs a novel acoustic mixing technique to coat spherical C103 powder particles with a uniform distribution of sub-200 nanometer yttria particles. During laser powder bed fusion additive manufacturing, layer-by-layer remelting disperses these yttria particles uniformly throughout the component microstructure. This eliminates the expensive, time-consuming mechanical alloying steps traditionally required for ODS alloys while enabling near-net-shape fabrication of complex geometries. Performance testing demonstrates substantial improvements: GRC103y exhibits double the yield strength at 800°C and 1.5x the yield strength at 1,400°C compared to baseline C103. The alloy also shows superior thermal stability: after one hour at 1,500°C, GRC103y retains 90% of its room temperature strength compared to only 67% for C103. Preliminary creep testing at 1,300°C and a stress of 50 MPa indicates significant improvements in creep resistance by 2539 times over baseline C103. Furthermore, GRC103y maintains excellent formability, allowing manufacturers to use traditional fabrication methods when desired. While NASA originally developed GRC103y for rocket propulsion and hypersonic vehicle applications, the alloy offers value across multiple industries. Aerospace companies can achieve weight savings or push systems to higher temperatures, while the alloy's compatibility with commercial oxidation coatings makes it suitable for environments requiring oxidation protection. GRC103y is currently available for patent licensing.
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