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NASA and the US Army Engineer Research and Development Center (ERDC) co-developed advanced graphene materials designed to improve the filtration rate of spacecraft water contaminants which could significantly extend the service life of existing media filtration beds. Traditional granulated activated carbon (GAC) media is characterized by having a polymodal pore structure and contains micro-, meso-, and macropores that trap and contain contaminants. By using the referenced method to add graphene nanoparticles to an existing GAC filtering substrate, additional filtering can be achieved due to graphene’s mostly mesoporous nature. A high-level overview of the graphene loading process is thus: The unloaded graphene nanoparticles are mixed with a water-based graphene suspension for an extended time at room temperature. This “graphene bath” process is repeated several times before the now graphene-loaded (up to ~ 1% by mass) filtration media is dried and prepared for packing into a filter cartridge. The graphene suspension used during the loading process may be reused multiple times, reducing consumables in the process. Laboratory testing has shown a 40x improvement in contaminant removal per mass of the absorbent (i.e., graphene) over the state of the art (granulated activated carbon) at lower loading rates, suggesting significant promise of the treated filter media posing a potential solution to the demands of an entire mission lifecycle. Potential commercial applications for this graphene loading method may lay in four distinct market segments that rely on filtration media beds (outside of aerospace): industrial filtration such as ultra-pure water refining for the semiconductor industry, commercial filtration, residential filtration, and filtration-as-a-service. Graphene nano-particles’ tunable pore sizing, in conjunction with this loading method, could offer tailored filtration boosting for existing water filter substrates. The Graphene Loading Method for Water Filtration Media has a technology readiness level (TRL) 4 (Component and/or breadboard validation in laboratory environment), and it is now available for patent licensing. Please note that NASA does not manufacture products itself for commercial sale.

There is a significant need for an inexpensive biological approach to recover specific, targeted metals and other target materials in e-waste or other aqueous solutions that requires minimal input of resources, including energy. This invention is a method of removing or adsorbing a target substance or material, for example, a metal, non-metal toxin, dye, or small molecule drug, from solution, by functionalizing a substrate with a peptide configured to selectively bind to the target substance or material and to bind to the substrate. The substrate is fungal mycelium, and the naturally-occurring or bioengineered peptide is called a target-binding domain, which is chemically bonded to a selected solid substrate. The target chemical species binds to the target-binding domain and is removed from solution. The target can be any chemical species dissolved or suspended in the solution. Capture of the target by the substrate can isolate and allow removal of the target substance from solution, or for utilization in water filtration, or recovery of targeted chemical species from solution, particularly aqueous solution applications. The peptides used include (i) fusion peptides and/or proteins containing metal-binding domain sequence and optionally containing substrate-binding domain sequence; (ii) fusion peptides/proteins containing a metal-binding domain and a chitin-binding domain; and (iii) nucleic acids encoding fusion peptides and/or proteins containing metal-binding domain sequence. The technology enables simple scale up to a level that could be successfully implemented in an environment with limited resources, such as on a space mission or on earth in developing countries with poor access to clean water.

The technology provides miniaturized techniques for extracting trace amounts of organic molecules (lipids) from natural samples. It operates as an autonomous, miniaturized fluidic system, integrating lab techniques for lipid analysis while minimizing reagent volumes and concentrating organics for analysis, thereby increasing signal-to-noise ratios by orders of magnitude. The non-aqueous fluidic system described herein for astrobiological and life-detection missions (either in situ or returned sample) is configured to extract lipid organics from regolith using (1) a fluidic sample processor made of materials compatible with organic solvents and (2) a machine-learning system to select processing steps and parameters to maximize lipid yield. A critical gap is bridged by integrating technologies into a system that replicates analytical lab procedures autonomously on a spaceflight instrument scale with fidelity to original lab techniques. Automated fluidic devices combine controlled handling of liquids with sequential operations and parallelization of replicate processes. By designing such systems to closely interface with both sample-delivery and analytical measurement systems, laboratory analyses are automated. The technology adapts best practice laboratory methods for lipid analysis, overcoming analytical challenges like low organic abundance, interference of minerals/salts, and degradation of origin-diagnostic molecular structures. The extraction and concentration techniques from rock/soil samples can be applied to any biomarkers by changing the solvent, temperature, and agitation.

NASA’s Carbon Capture Filter was designed to trap solid carbon dust through a variety of mechanisms. These include inertial separation, flow recirculation, flow tortuosity, media filtration, and quenching of hot particles or of precursor particles from pyrolysis. The filter uses a custom-designed housing to produce a strong and large recirculating pattern to remove dust through inertial forces and confine it into a large collection cup, which is enshrouded in a cold trap (using a thermoelectric cooler) to thermally induce precipitation of the solid carbon. The flow then passes through a single stage baffle and tube filters before exiting through the outlet at the top of the housing. During operations, gaseous carbon-containing streams enter the filter via an inlet tube at the top of the housing. The inlet tube extends down towards the bottom of the collection cup, where the high-speed stream meets a sudden perpendicular bottom wall, inducing a stagnation flow. Large particles inertially separate from the flow and impinge onto the bottom wall. The partial enclosure of the collection cup (aside from a small slit connecting it to the upper chamber) causes a recirculation bubble to form, increasing the residence time of the stream. The vortical motion of the recirculation bubble causes the large particles to spin outwards towards the walls of the collection cup. The collection cup is cooled to quench the carbon particles, causing them to precipitate out and collect on the walls of the cup. The extended residence time caused by the recirculating flow further quenches the stream. Only small particles that are entrained sufficiently by the flow make it through the slit between the collection cup and upper chamber. On the top wall of the upper chamber, an array of tubular filters collects the remaining particles before the gaseous stream exits the system. NASA’s Carbon Capture Filter has been prototyped and undergone initial testing with simulant dust, yielding promising results. The invention is available for licensing to industry.

In the event of a fire aboard the Orion Spacecraft, the Portable Fire Extinguisher (PFE) can introduce up to three pounds of water into the cabin to extinguish a fire. A filter was needed to work in conjunction with the Orion Fire Safety System (OFSS) to filter water out of the cabin atmosphere after dispersal from the PFE. Airflow introduced to the smoke filter of the OFSS must be dry and free of large particulates for the sorbent material to effectively extract smoke generated by a fire. These moisture and particulate concerns prompted a re-design of the original filter, especially a filter that could be tested in Earth’s gravity and yielding results that would transfer to a microgravity environment. The newly designed filter uses a multi-phase flow separation method that allows the airflow to develop fully in a helical flow path. This flow path resides within a wicking material used to separate the liquid from the gas (air) while also trapping particulate matter. Helical flow paths implemented in the filter impart a centrifugal force upon the incoming gas/liquid mixture that develops an asymmetric liquid film on the inner contour of the helix. Upon active airflow, the larger water droplets are inertially forced into the inner contour flow path wall. The flow path walls are made from a wicking material, and all liquid film and liquid droplets that are inertially deposited onto the walls are adsorbed into the filter material. The resulting output flow from the filter is 100% gas. The Corkscrew Filter has a technology readiness level (TRL) of 5 (component and/or breadboard validation in relevant environment) and is now available for patent licensing. Please note that NASA does not manufacture products itself for commercial sale.