Abnormal Grain Growth Suppression in Aluminum Alloys

Dispersion Enhanced Aluminum Alloys improve the additive manufacturing performance of high-strength aluminum alloys by modifying the alloy powder with uniformly dispersed nano-sized ceramic particles. Building on the dispersion and acoustic mixing methods developed during the creation of NASA Glenn's GRX-810 technology, researchers use an acoustic field to attach nanoscale alumina dispersoids to the surface of each aluminum alloy powder particle. During mixing, acoustic energy creates rapid micro-vibrations that cause the alumina particles to collide with the metal powder, embed against its surface, and distribute into a uniform shell that surrounds each particle. This produces a composite powder in which every aluminum particle carries its own evenly spaced ceramic nucleation sites. When the composite powder is delivered into an additive manufacturing process such as laser powder bed fusion or directed energy deposition, the aluminum alloy melts while the alumina dispersoids remain solid due to their significantly higher melting temperature. As the molten pool flows and mixes, the dispersoids remain suspended throughout the liquid region. During solidification, these solid particles interrupt grain growth and serve as nucleation points that promote the formation of fine equiaxed grains. This refined microstructure distributes thermal stresses more uniformly and disrupts the crack initiation mechanisms that typically occur in high-strength alloys like AA 2050. By stabilizing the alloy during solidification, the technology enables these advanced materials to be printed with greater reliability, improved geometric control, and more consistent mechanical behavior across the final product. The enhanced alloy technology is available for patent licensing.

Via this NASA innovation, a product is first heated to a temperature within the range of 204 to 343 degrees C for an extended soak of up to 16 hours. The product is then slowly heated to a second temperature within the range of 371 to 482 degrees C for a second soak of up to 12 hours. Finally, the product is slowly cooled to a final soak temperature of 204 to 343 degrees C before cooling to room temperature. The product so treated will exhibit greatly improved formability. To date, the low formability issue has limited the use of lightweight Al-Li alloys for large rocket fuel tank dome applications. Manufacturing a dome by stretch forming typically requires multiple panels as well as multiple welding and inspection steps to assemble these panels into a full-scale fuel tank dome. Complex tensile and bending stresses induced during the stretch forming operations of Al-Li alloys have resulted in high rates of failure for this process. To spin form a large rocket dome, the spin blank must be prepared by joining smaller plates together using friction stir welding. However, friction stir welding produces a distinct metallurgical structure inside and around the friction stir weld that makes it very susceptible to cracking during spin forming.

Glenn researchers have optimized how shape memory alloys (SMAs) are trained by reconceptualizing the entire stabilization process. Whereas prior techniques stabilize SMAs during thermal cycling, under conditions of fixed stress (known as the isobaric response), what Glenn's innovators have done instead is to use mechanical cycling under conditions of fixed temperature (the isothermal response) to achieve stabilization rapidly and efficiently. This novel method uses the isobaric response to establish the stabilization point under conditions identical to those that will be used during service. Once the stabilization point is known, a set of isothermal mechanical cycling experiments is then performed using different levels of applied stress. Each of these mechanical cycling experiments is left to run until the strain response has stabilized. When the stress levels required to achieve stabilization under isothermal conditions are known, they can be used to train the material in a fraction of the time that would be required to train the material using only thermal cycling. As the strain state has been achieved isothermally, the material can be switched back under isobaric conditions, and will remain stabilized during service. In short, Glenn's method of training can be completed in a matter of minutes rather than in days or even weeks, and so SMAs become much more practical to use in a wide range of applications.

Shape memory alloys (SMAs) are metals that can return to their original shape following thermal input and are largely used as actuators for various applications across industries including space, aeronautics, automotive, and biomedical. These alloys can require long processing times to stabilize through repeated training cycles and suffer from loss of strength and stability during use. Precipitation strengthening (using heat treatments to grow small nanoscale regions of distinct metal phases within the base alloy) is one way to mitigate these issues. The NASA inventors have combined a modification of typical NiTi compositions by introducing Palladium (Pd) and small amounts of other metals and specific heat treatments to produce a novel SMA with improved properties. Specifically, the alloy is inherently stable, reducing both the need for extended processing times to stabilize the metal and the possibility of failure during high numbers of actuation cycles. Further, the SMA is specifically designed to have significantly lower hysteresis (the temperature difference between the heating and cooling) than current state of the art SMAs, i.e., at or below 10°C compared to 20°C or above. These properties combine for a SMA with enhanced properties usable across various industries and applications for reliable actuation. The related patent is now available to license. Please note that NASA does not manufacturer products itself for commercial sale.

Ultrasonic Stir Welding is a solid state stir welding process, meaning that the weld work piece does not melt during the welding process. The process uses a stir rod to stir the plasticized abutting surfaces of two pieces of metallic alloy that forms the weld joint. Heating is done using a specially designed induction coil. The control system has the capability to pulse the high-power ultrasonic (HPU) energy of the stir rod on and off at different rates from 1-second pulses to 60-millisecond pulses. This pulsing capability allows the stir rod to act as a mechanical device (moving and stirring plasticized nugget material) when the HPU energy is off, and allowing the energized stir rod to transfer HPU energy into the weld nugget (to reduce forces, increase stir rod life, etc.) when the HPU energy is on. The process can be used to join high-melting-temperature alloys such as titanium, Inconel, and steel.