Synthesis and Development of Polyurethane Coatings Containing Fluorine Groups for Adhesive Applications

This technology is a copolymeric epoxy coating that is loaded with a fluorinated aliphatic chemical species and nano- to microscale particle fillers. The coating was developed as a hydrophobic and non-wetting coating for aerodynamic surfaces to prevent accumulation of insect strike remains that can lead to natural laminar flow disruption and aerodynamic inefficiencies. The coating achieves hydrophobicity in two ways. First, the fluorinated aliphatic chemical species are hydrophobic surface modification additives that preferentially migrate to the polymer surface that is exposed to air. Secondly, the incorporation of particle fillers produces a micro-textured surface that displays excellent resistance to wetting. Combined, these two factors increase hydrophobicity and can also be used to readily generate superhydrophobic surfaces.

The technology is a method of mitigating insect residue adhesion to various surfaces upon insect impact. The process involves topographical modification of the surface using laser ablation patterning followed by chemical modification or particulate inclusion in a polymeric matrix. Laser ablation patterning is performed by a commercially available laser system and the chemical spray deposition is composed of nanometer sized silica particles with a hydrophobic solution (e.g. heptadecafluoro-1,1,2,2-tetrahydrodecyltriethoxysilane) in an aqueous ethanol solution. Both topographic and chemical modification of the substrate is necessary to achieve the desired performance.

According to the International Air Transport Association statistics, the annual fuel cost for the global airline industry is estimated to be about $140 billion in 2017. Therefore, fuel cost is a major cost driver for the airline industry. Advanced future transport aircraft will likely employ adaptive wing technologies that enable the wings of those aircraft to adaptively reconfigure themselves in optimal shapes for improved aerodynamic efficiency throughout the flight envelope. The need for adaptive wing technologies is driven by the cost of fuel consumption in commercial aviation. NASA Ames has developed a novel way to address aerodynamic inefficiencies experienced during aircraft operation. The real-time drag optimization control method uses an on-board, real-time sensor data gathered from the aircraft conditions and performance during flight (such as engine thrust or wing deflection). The sensor data are inputted into an on-board model estimation and drag optimization system which estimates the aerodynamic model and calculates the optimal settings of the flight control surfaces. As the wings deflect during flight, this technology uses an iterative approach whereby the system continuously updates the optimal solution for the flight control surfaces and iteratively optimizes the wing shape to reduce drag continuously during flight. The new control system for the flight control surfaces can be integrated into an existing flight control system. This new technology can be used on passenger aircraft, cargo aircraft, or high performance supersonic jets to optimize drag, improve aerodynamic efficiency, and increase fuel efficiency during flight. In addition, it does not require a specific aircraft math model which means it does not require customization for different aircraft designs. The system promises both economic and environmental benefits to the aviation industry as less fuel is burned.

Low ice adhesion strength coatings are only useful insofar as they remain on the surface of interest, and aircraft leading edges experience extreme environmental conditions during flight. Ensuring durability while maintaining performance – in this case, reduction of impact (i.e., accreted in-flight) ice adhesion strength – is critical to meeting the needs of the aviation industry and other commercial applications. To that end, NASA engineers investigated coating compositions comprised of epoxy resins, including aromatic and aliphatic resins, and aromatic diamine hardeners. Several nonreactive additives were incorporated and tested. The first was holey graphene, a unique nanomaterial made by partly oxidizing areas of graphene that already have defects. This creates high energy functionalities that result in good dispersion throughout the matrix, enabling the mechanical properties of graphene to be imparted throughout the coating. Secondly, micrometer-sized core-shell rubber particles were dispersed throughout the epoxy resin to increase toughness. Finally, a series of polyhedral oligomeric silsequixones (POSS) were used for mechanical reinforcement. Several different coating formulations were development and tested, each incorporating different relative amounts of additives, with good results. Thus, the coatings can be tailored to meet different application-specific requirements. NASA's coating formulations, with further development, may be suitable for in-flight (i.e., impact) ice adhesion reduction on aircraft leading edges and other platforms exposed to harsh environments.

Gust loads may have detrimental impacts on flight including increased structural and aerodynamic loads, structural deformation, and decreased flight dynamic performance. This technology has been demonstrated to improve current gust load alleviation by use of a trailing-edge, free-floating surface control with a mass balance. Immediately upon impact, the inertial response of the mass balance shifts the center of gravity in front of the hinge line to develop an opposing aerodynamic force alleviating the load felt by the wing. This passive gust alleviation control covering 33% of the span of a cantilever wing was tested in NASA Langleys low speed wind tunnel and found to reduce wing response by 30%. While ongoing experimental work with new laser sensing technologies is predicted to similarly reduce gust load, simplicity of design of the present invention may be advantageous for certification processes. Additionally, this passive technology may provide further gust alleviation upon extending the use of the control to the entire trailing edge of the wing or upon incorporation with current active gust alleviation systems. Importantly, the technology can be easily incorporated into to the build of nearly all fixed wing aircrafts and pilot control can be maintained through a secondary trim tab. Though challenging to retrofit, passive gust alleviation could enable use of thinner, more efficient wings in new plane design.