Chemical and Topographical Surface Modifications for Insect Adhesion Mitigation

Coatings offer an advantage over previous strategies due to ease of application, potentially negligible weight penalty, reduced environmental concerns, better economics, and continual function throughout the flight profile. In this present innovation, a particular coating has been developed that is similar to the basic component of a majority of aerospace coatings used on commercial aircraft. This coating was then sprayed from a solvent on various substrates. Once spray-coated on a substrate and dried, the coatings were then tested for adhesion mitigation of insect residues in a controlled insect impact facility propelled toward the engineered surface at approximately 150 mph. Once impacted, these coatings demonstrated hydrophobicity and a significant reduction in contaminant adhesion. The coatings were further tested in an operational environment on the eco-demonstrator Boeing 757 aircraft. The coatings resulted in lower insect accumulation than the control surface (no coating). The durability of these coatings was comparable to state-of-the-art formulations and satisfies current aircraft manufacturing requirements. These coatings likely have advantageous use in aerospace applications, wind turbine systems, and automotive industry, among other industries. This innovation not only appears to solve a problem that has persisted, thus fulfilling an unmet need, but also comprises a new composition of matter that can lead to numerous unforeseen applications.

This technology is a copolymeric epoxy coating that is loaded with a fluorinated aliphatic chemical species and nano- to microscale particle fillers. The coating was developed as a hydrophobic and non-wetting coating for aerodynamic surfaces to prevent accumulation of insect strike remains that can lead to natural laminar flow disruption and aerodynamic inefficiencies. The coating achieves hydrophobicity in two ways. First, the fluorinated aliphatic chemical species are hydrophobic surface modification additives that preferentially migrate to the polymer surface that is exposed to air. Secondly, the incorporation of particle fillers produces a micro-textured surface that displays excellent resistance to wetting. Combined, these two factors increase hydrophobicity and can also be used to readily generate superhydrophobic surfaces.

The following methods can be used individually or in combination to generate superhydrophobic surfaces: Synthesis of novel copolyimide oxetanes with unique surface properties The technology is the synthesis of a polyimide coating or film with a modified surface chemistry shown in Figure 1. A minor amount of an oxetane reactant containing fluorine is added to the polyimide, and the oxetane preferentially migrates to the surface, enabling relatively high concentrations of fluorine at the surface, without compromising the functional performance of the bulk of the polymide coating/film. The copolymers exhibit mitigation of particle adhesion and fouling from exposure to various particulate and biological contaminants and exhibit reduced surface energy and increased surface fluorine content at extremely low oxetane loadings relative to the imide matrix (see Figure 2). Additionally, the short fluorinated carbon chains do not bioaccumulate, reducing the environmental impact of these materials. Modifying surface energy via laser ablative surface patterning This method uses a laser to create nanoscale patterns in the surface of a material to increase the hydrophobicity of the surface (see Figure 2). The benefits of hydrophobic surfaces include decreases in friction and increases in self-cleaning properties. This is an advantageous method of surface modification because it is fast and single-step, promises to be scalable, requires no chemicals, could be applied to a variety of materials, and does not require a planar surface for patterning.

In addition to previous LOTUS coating formulations, an additional optical formulation may be applied via vacuum deposition. This coating forms a top layer and may be applied in different thicknesses that serve to enhance its hydrophobic properties. The vacuum deposited material may comprise fluorinated ethylene propylene or a similar material. This coating is transparent and can be used on optical components or any other applications requiring a clear coating.

Previous techniques for measuring dust accumulation, mostly de-pendent on solar cell output, were limited by their inability to distin-guish dust effects from other factors like incident radiation and radiation damage. These techniques were less effective in environ-ments with inconsistent solar flux and future missions, such as the Lunar South Pole, and lacked versatility in adapting to diverse envi-ronmental conditions. The PADS device embraces success over these challenges, and reflects enhanced features over prior iterations to also allow for space environments. Key design features begin with the customizable mechanical design of the PADS device for use in space environments, heaters with imbedded precision temperature sensors, a selected optical coating for the device coupons that are calibrated on high-fidelity thermal modeling and validated with ground-based testing to simulate the space environment of interest (including dusting with simulants representative of the planetary-body soil/regolith), and a control circuit for precision control/matching of the thermal inputs to the sensor via the heaters. Retainers with mount isolators are implemented to ensure the stacked layers within the device do not dislodge during high vibration or gravitational loads during launch. For operation, the PADS device is installed at the point of interest (e.g., space vehicle surface, extraterrestrial equipment) to quantify dust accumulation. Power and data transfer are done through cabling to the space vehicle system or can be provided standalone. A control circuit/algorithm adjusts the power to the heaters to precisely match the temperature setpoints. Ground testing in the simulated space environment conditions of interest creates a calibration plot of effec-tive emittance versus dust density, and allows determination of the degradation in emittance as the dust increases on the surface. Testing on the PADS device has been completed in a simulated lunar environment and data has been collected to enable sensor calibration for its use on the Moon. It is currently poised for integration into a lander for flight testing. Although the PADS device is intended for use in a burgeoning space industry and requisite environments – but given that the PADS device is partially comprised of programmable sensors in conjunction with optically coated coupons that can be tailored for custom use - it or its constituent components could be modified for terrestrial applications such as surface dust monitoring on photovoltaic panels or potentially combustible dust on various industrial surfaces.