Atomic Number (Z)-Grade Radiation Shields from Fiber Metal Laminates

Materials and Coatings
Atomic Number (Z)-Grade Radiation Shields from Fiber Metal Laminates (LAR-TOPS-201)
Shapeable radiation shields
Overview
NASA Langley Research Center has developed a shapeable radiation shield made from fiber metal laminates. The technology was developed based on a need for better performing shielding of sensitive spacecraft electronics. Beyond spacecraft electronics, the invention has uses for radiation protective clothing, radioactive fluid piping shields, nuclear reactor shields, and other applications.

The Technology
This technology is a flexible, lighter weight radiation shield made from hybrid carbon/metal fabric and based on the Z-grading method of layering metal materials of differing atomic numbers to provide radiation protection for protons, electrons, and x-rays. To create this material, a high density metal is plasma spray-coated to carbon fiber. Another metal with less density is then plasma spray-coated, followed by another, and so on, until the material with the appropriate shielding properties is formed. Resins can be added to the material to provide structural adhesion, reducing the need for mechanical bonding. This material is amenable to molding and could be used to build custom radiation shielding to protect cabling and electronics in situations where traditional metal shielding is difficult to place.
Images of titanium, tantalum, and copper carbon fiber fabrics.  Laminates can be made out of autoclave with vacuum assisted resin transfer molding (VARTM).
Benefits
  • Flexible, moldable, and can be made for custom, hard-to-shield locations
  • Less weight than traditional radiation shielding for electrons and x-rays
  • Shield can be integrated with resins to provide easy adhesion

Applications
  • Radiation protection for electronic instrumentation
  • Nuclear reactor shields
  • Radioactive fluid piping shields
  • Radiation protection clothing
  • Spacecraft and satellite shielding
Technology Details

Materials and Coatings
LAR-TOPS-201
LAR-17919-2 LAR-17919-3 LAR-18586-1-CON LAR-17919-1 LAR-18586-2-CON
NASA Shields 1: A Radiation Shielding Experiment Developed with Radiation Modeling. Dr. Larry Thomsen, GESNT 4 13th Space Users Workshop, November 28, 2018. https://www.google.com/url?sa=t&rct=j&q=&esrc=s&source=web&cd=&ved=2ahUKEwixosqe4uaCAxXoKlkFHf_VA3QQFnoECBMQAQ&url=https%3A%2F%2Findico.esa.int%2Fevent%2F249%2Fcontributions%2F4193%2Fattachments%2F3250%2F4219%2FNASA_Shields-1_29NOV18_Thomsen_GEANT4_13th_Space_Users_Workshop.pdf&usg=AOvVaw1cZpNGR8uKGgcc4iJim6xA&opi=89978449.

YouTube https://youtu.be/oHA8j5bpFcU?si=7koSPeoGzVvYB3FK.
Similar Results
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Flexible Lightweight Radiation Shielding
The thin, lightweight radiation shielding is comprised of a low Z/high Z/low Z layered structure wherein the low Z layer is composed of titanium and the high Z layer is composed of either tantalum or antimony. Modelling of radiation shielding performance from a Cobalt 57 source shows a 10 times reduction in gamma radiation when using tantalum and a 25 times reduction when using antimony as compared with a single layer of lead. In addition, the Z-shielding is 25% lighter than a single lead layer with the same thickness (0.35-0.36 mm). The direct textile spraying innovation outlined by this invention enables the ability to shape this shielding into garments via the sewing of metal coated fibers. The refractory metal shielding can be added onto a variety of commodity-based fabrics including glass fabrics.
Purchased from Shutterstock on 1/13/2022. Licence 1594544836
High Atomic Number Coatings for Fabrics
High atomic number materials, such as tantalum, do not bond well to oxygen- and hydroxyl-rich surfaces, such as glass fibers. These metals often form surface oxides when layered on glass fabric, resulting in flaking of the high atomic number material off the fabric during cutting, folding, and/or handling. To improve coating durability, this invention applies a lower atomic number metal as a tie down layer first before applying the high atomic number metal layer. The tie down layer reduces oxide formation between the substrate and the high atomic number material, promoting adhesion. Titanium has shown strong adhesion with different metals and is effective at reducing oxide formation when diffusion bonded to itself or other materials. It has been shown to be effective at improving durability when thermally sprayed onto a glass fiber fabric as a tie down layer for a subsequent tantalum layer (also applied via RF plasma spray). The titanium layer is only approximately 1 mil thick but results in strong adhesion of the tantalum layer by inter-metallic or diffusion bonding. A thermal spray process may be used, as well. This innovation enables the delivery of high atomic metal coating on glass fiber fabrics and other polymeric substrates that are lower cost, lighter weight, and durable to form a flexible cloth material with Z-graded radiation shielding. Coated samples have been produced and the technology is currently at a technology readiness level (TRL) of 4 (prototype).
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