Particle Contamination Mitigation Methods

materials and coatings
Particle Contamination Mitigation Methods (LAR-TOPS-97)
Unique surface properties such as increased hydrophobicity and self-cleaning
Overview
NASA's Langley Research Center researchers offer you methods for particle contamination mitigation. The methods were developed for exploration of surfaces such as Moon, Mars, and asteroids. During past missions, lunar dust caused an array of issues including compromised seals, clogged filters, abraded visors and space suit surfaces, and was a significant health concern. NASA's novel methods for particle contamination mitigation include both controlled chemical and topographical modifications. These methods offer a wealth of applications and commercial opportunities. The benefits include films, coatings, and surface treatments with antifouling, dust resistance, hydrophobic to superhydrophic, low adhesion/friction, and self-cleaning characteristics. NASA is seeking development partners.

The Technology
The following methods can be used individually or in combination to generate superhydrophobic surfaces: Synthesis of novel copolyimide oxetanes with unique surface properties The technology is the synthesis of a polyimide coating or film with a modified surface chemistry shown in Figure 1. A minor amount of an oxetane reactant containing fluorine is added to the polyimide, and the oxetane preferentially migrates to the surface, enabling relatively high concentrations of fluorine at the surface, without compromising the functional performance of the bulk of the polymide coating/film. The copolymers exhibit mitigation of particle adhesion and fouling from exposure to various particulate and biological contaminants and exhibit reduced surface energy and increased surface fluorine content at extremely low oxetane loadings relative to the imide matrix (see Figure 2). Additionally, the short fluorinated carbon chains do not bioaccumulate, reducing the environmental impact of these materials. Modifying surface energy via laser ablative surface patterning This method uses a laser to create nanoscale patterns in the surface of a material to increase the hydrophobicity of the surface (see Figure 2). The benefits of hydrophobic surfaces include decreases in friction and increases in self-cleaning properties. This is an advantageous method of surface modification because it is fast and single-step, promises to be scalable, requires no chemicals, could be applied to a variety of materials, and does not require a planar surface for patterning.
sail boat FIGURE 2 - Water droplet with varying surface modifications. Image Credit: NASA
Benefits
  • Antifouling
  • Dust resistant
  • Hydrophobic to superhydrophobic
  • Low adhesion/friction
  • Self-cleaning

Applications
  • Biological templating
  • Biomedical devices
  • Corrosion and stain resistance
  • Drag reduction
  • Reduced ice and water adhesion
  • Reduced insect adhesion on aircraft/ automobiles
  • Marine antifouling coatings
  • Microfluidics
  • Particle and biological contaminant mitigation
  • Self-cleaning of many kinds of surfaces
  • Sensors
  • Surface-specific chemical sensing
Technology Details

materials and coatings
LAR-TOPS-97
LAR-17769-1 LAR-18026-1 LAR-17769-2 LAR-18026-2 LAR-18026-3 LAR-18026-4
Similar Results
Self-Cleaning Coatings for Space or Earth
The new transparent EDS technology is lighter, easier to manufacture, and operates at a lower voltage than current transparent EDS technologies. The coating combines an optimized electrode pattern with a vapor deposited protective coating of SiO2 on top of the electrodes, which replaces either polymer layers or manually adhered cover glass (see figure on the right). The new technology has been shown to achieve similar performances (i.e., over 90% dust clearing efficiency) to previous technologies while being operated at half the voltage. The key improvement of the new EDS coating comes from an innovative method to successfully deposit a protective layer of SiO2 that is much thinner than typical cover glass. Using vapor deposition enables the new EDS to scale more successfully than other technologies that may require more manual manufacturing methods. The EDS here has been proven to reduce dust buildup well under vacuum and may be adapted for terrestrial uses where cleaning is done manually. The coatings could provide a significant improvement for dust removal of solar cells in regions (e.g., deserts) where dust buildup is inevitable, but water access is limited. The EDS may also be applicable for any transparent surface that must remain transparent in a harsh or dirty environment. The related patent is now available to license. Please note that NASA does not manufacturer products itself for commercial sale.
Lotus Coating
Lotus Coating
This durable, transparent, nano-textured coating can be applied via a wet chemistry process to variety of rigid and flexible surfaces by spin coating, brush application, or spray application, making it applicable for many purposes beyond space flight and aeronautical applications. The coatings unique nano-textured surface and overcoat reduces surface energy and contact surface area, giving the coating anti-contamination and self cleaning properties that minimize dust, liquid, and ice accumulation on its surface, similar to a leaf on the Lotus plant. The coating is low outgassing, stable in vacuum, and can survive harsh spaceflight environments. Depending on requirements, the Lotus Coating can be tailored to fit the specific needs of a project or customer. This customization makes the Lotus system far more adaptive, allowing for a more diverse range of applications.
View through a P-3 window of a small grounded portion of the terminus of Upernavik Central, northwest Greenland, as seen during an Operation IceBridge flight
Alternative Transparent Coating Lotus Suitable for Optics with Vacuum Deposition Layer
In addition to previous LOTUS coating formulations, an additional optical formulation may be applied via vacuum deposition. This coating forms a top layer and may be applied in different thicknesses that serve to enhance its hydrophobic properties. The vacuum deposited material may comprise fluorinated ethylene propylene or a similar material. This coating is transparent and can be used on optical components or any other applications requiring a clear coating.
NASA Space Station Image
Multi-Stage Filtration System
While HEPA filter elements can last for years without intervention, pre-filtering systems that remove larger particles before they reach the HEPA filter need to be treated (most often by cleaning or replacement) as often as once a week. These treatments can be resource-intensive and expensive, especially in extreme environments. Glenn's innovative system combines a pre-filtration impactor and a scroll filter that reduces the need to replace the more sensitive or expensive filters, extending the system's working life. The system uses an endless belt system to provide the impaction surface. A thin layer of low-toxicity grease is applied to the impaction surface to increase particle adhesion. A high flow turning angle near the impaction surface causes relatively large particles to impact and stick to the surface while smaller particles stay within the air flow. When the surface is covered with particles - or if a layer of particles has grown to a thickness that impairs adhesion - the surface is regenerated. The band is rotated so that the loaded surface passes by a scrapper, removing the layer of particles and a clean segment of the band revolves to become the new impaction surface. A further innovation is the scroll filter which allows the filtration media to be rotated out of the airflow when fully loaded, providing multiple changes of the filter through a motorized scrolling or indexing mechanism. When nearly fully loaded with dust particles, the exposed media is mechanically rolled up on one side of the filter to both contain and compactly store the dust. The spools that hold the clean and spent filter media are mounted on roller bearings to facilitate the scrolling operation and reduce motor power requirements. Nearly any grade of filter media can be used to meet the desired filtration specification. Additional media rolls can be added after the original roll is spent to further increase filter life.
Bug on metal
Chemical and Topographical Surface Modifications for Insect Adhesion Mitigation
The technology is a method of mitigating insect residue adhesion to various surfaces upon insect impact. The process involves topographical modification of the surface using laser ablation patterning followed by chemical modification or particulate inclusion in a polymeric matrix. Laser ablation patterning is performed by a commercially available laser system and the chemical spray deposition is composed of nanometer sized silica particles with a hydrophobic solution (e.g. heptadecafluoro-1,1,2,2-tetrahydrodecyltriethoxysilane) in an aqueous ethanol solution. Both topographic and chemical modification of the substrate is necessary to achieve the desired performance.
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