Rapid Fabrication of Boron Nitride Fine Fibers

Sometimes called white graphite, affordable and plentiful hBN possesses the same kind of layered molecular structure as graphite. In graphite, this structure has allowed next-generation nanomaterials like carbon nanotubes and graphene to be produced. With hBN, however, the process of converting the substance into boron nitride nanotubes (BNNT) has been too difficult to yield commercial quantities. Glenn innovators have created several new methods that could enable greater adoption of this unique nanomaterial. In the initial stage, the starter reactant is mixed with a selected set of chemicals (a metal chloride, for example) and an activation agent (such as sodium fluoride). This mixture causes hBN to become less resistant to intercalation. The intercalated product can then be exfoliated by heating the material in air, and giving the material a final rinse with a liquid-phase ferric chloride salt to dissolve any embedded impurities without damaging its internal structure. These efficiently exfoliated nanomaterials can be used to form advanced composite materials (e.g., layered with aluminum oxide to form hBN/alumina ceramic composites). Nanomaterials fabricated from hBN can also take advantage of the material's unique combination of being an electrical insulator with high thermal conductivity for applications ranging from microelectronics to energy harvesting. Glenn's innovations have enabled a significantly improved matrix composite material with the potential to make a significant impact on the commercial materials market.

The new composite developed by NASA incorporates PGS and CNTs to enhance its thermal conductivity while preserving the mechanical properties of the underlying carbon fiber polymer composite. NASA has also improved the composite manufacturing process to ensure better thermal conductivity not only on the surface, but also through the thickness of the material. This was achieved by adding perforations that enable the additives to spread through the composite. The process for developing this innovative, highly thermally conductive hybrid carbon fiber polymer composite involves several steps. Firstly, a CNT-doped polymer resin is prepared to improve the matrix's thermal conductivity, which is then infused into a carbon fiber fabric. Secondly, PGS is treated to enhance its mechanical interface with the composite. Thirdly, perforation is done on the pyrolytic graphite sheet to improve the thermal conductivity through the thickness of the material by allowing CNT-doped resin to flow and better interlaminar mechanical strength. Finally, the layup of PGS and CNT-CF polymer is optimized. Initial testing of the composite has shown significant increases in thermal conductivity compared to typical carbon fiber composites, with a more than tenfold increase. The composite also has higher thermal conductivity than aluminum alloys, with more than twice the thermal conductivity of the Aluminum 6061 typically used in the aerospace industry. For this new material, NASA has completed a proof-of-concept demonstration and work continues to use the material in a heat exchanger system and further characterize the properties including longevity and radiation impact analysis.

Carbon nanotubes (CNTs) show promise for multifunctional materials for a range of applications due to their outstanding combination of mechanical, electrical and thermal properties. However, these promising mechanical properties have not translated well to CNT nanocomposites fabricated by conventional methods due to the weak load transfer between tubes or tube bundles. In this invention, the carbon nanotube forms such as sheets and yarns were modified by in-situ polymerization with polyaniline, a -conjugated conductive polymer. The resulting CNT nanocomposites were subsequently post-processed to improve mechanical properties by hot pressing and carbonization. A significant improvement of mechanical properties of the polyaniline/carbon nanotube nanocomposites was achieved through a combination of stretching, polymerization, hot pressing, and carbonization.

The low density flexible ablator can be deployed by mechanical mechanisms or by inflation and is comparable in performance to its rigid counterparts of the same density and composition. Recent testing in excess of 400W/cm2 demonstrated that the TPS char has good structural integrity and retains similar flexibility to the virgin material, there by eliminating potential failure due to fluttering and internal stress buildup as a result of pyrolysis and shrinkage of the system. These flexible ablators can operate at heating regimes where state of the art flexible TPS (non-ablative) will not survive. Flexible ablators enable and improve many missions including (1) hypersonic inflatable aerodynamic decelerators or other deployed concepts delivering large payload to Mars and (2) replacing rigid TPS materials there by reducing design complexity associated with rigid TPS materials resulting in reduced TPS costs.

There has been much interest in developing polymeric nanocomposites with ultrahigh thermal conductivities, such as with exfoliated graphite or with carbon nanotubes. These materials exhibit thermal conductivity of 3,000 W/mK measured experimentally and up to 6,600 W/mK predicted from theoretical calculations. However, when added to polymers, the expected thermal conductivity enhancement is not realized due to poor interfacial thermal transfer. This technology is a method of forming carbon-based fillers to be incorporated into highly thermal conductive nanocomposite materials. Formation methods include treatment of an expanded graphite with an alcohol/water mixture followed by further exfoliation of the graphite to form extremely thin carbon nanosheets that are on the order of between about 2 and about 10 nanometers in thickness. The carbon nanosheets can be functionalized and incorporated as fillers in polymer nanocomposites with extremely high thermal conductivities.