Innovative Shape Memory Metal Matrix Composites

The new SMC substrate has four components: a shape memory polymer separately developed at NASA Langley; a stack of thin-ply carbon fiber sheets; a custom heater and heat spreader between the SMC layers; and integrated sensors (temperature and strain). The shape memory polymer allows the as-fabricated substrate to be programmed into a temporary shape through applied force and internal heating. In the programmed shape, the deformed structure is in a frozen state remaining dormant without external constraints. Upon heating once more, the substrate will return slowly (several to tens of seconds) to the original shape (shown below). The thin carbon fiber laminate and in situ heating solve three major pitfalls of shape memory polymers: low actuation forces, low stiffness and strength limiting use as structural components, and relatively poor heat transfer. The key benefit of the technology is enabling efficient actuation and control of the structure while being a structural component in the load path. Once the SMC substrate is heated and releases its frozen strain energy to return to its original shape, it cools down and rigidizes into a standard polymer composite part. Entire structures can be fabricated from the SMC or it can be a component in the system used for moving between stowed and deployed states (example on the right). These capabilities enable many uses for the technology in-space and terrestrially.

SMAs are important multifunctional materials for the development of adaptive engineering structures. They exhibit a high work output that is competitive with, or superior to, conventional hydraulic, pneumatic, or electromagnetic actuators. While highly promising, SMAs are not always a practical alternative to conventional actuators because of their limited phase transformation temperatures and dimensional instability. Thanks to Glenn's innovative new SMA, that's about to change. Unlike traditional binary NiTi SMAs, Glenn's Ni-Ti-Hf-Zr SMA includes secondary, nanoscale precipitate phases that offer inherent dimensional stability to the material. Consequently, there is minimal to no need for training, resulting in much faster production times, lower processing costs, and a finished product with superior work outputs and better operational life. These Ni-rich alloys can be produced by Vacuum Induction Melting, Vacuum Arc Melting, Vacuum Arc Remelting, and Induction Skull Melting. Perhaps the most exciting characteristic of Glenn's SMA, however, is its ability to achieve a broad range of transformation temperatures suitable for high temperature (100 to 300°C), ambient, and sub-ambient temperature applications nearing -100°C. Furthermore, these temperatures can be tailored and fine-tuned though heat treatment to fit the needed parameters for the application of interest. In contrast, traditional NiTi SMAs exhibit fixed phase transformation at temperatures from slightly below room temperature to around 100°C. Glenn's Ni-Ti-Hf-Zr SMA opens the door to countless applications that can benefit from the unique properties of SMAs but require high durability and extreme temperature capability.

Glenn researchers have optimized how shape memory alloys (SMAs) are trained by reconceptualizing the entire stabilization process. Whereas prior techniques stabilize SMAs during thermal cycling, under conditions of fixed stress (known as the isobaric response), what Glenn's innovators have done instead is to use mechanical cycling under conditions of fixed temperature (the isothermal response) to achieve stabilization rapidly and efficiently. This novel method uses the isobaric response to establish the stabilization point under conditions identical to those that will be used during service. Once the stabilization point is known, a set of isothermal mechanical cycling experiments is then performed using different levels of applied stress. Each of these mechanical cycling experiments is left to run until the strain response has stabilized. When the stress levels required to achieve stabilization under isothermal conditions are known, they can be used to train the material in a fraction of the time that would be required to train the material using only thermal cycling. As the strain state has been achieved isothermally, the material can be switched back under isobaric conditions, and will remain stabilized during service. In short, Glenn's method of training can be completed in a matter of minutes rather than in days or even weeks, and so SMAs become much more practical to use in a wide range of applications.

Glenn's revolutionary SMARS device is fabricated from nickel-titanium-halfnium (NiTiHf), nickel-titanium-zirconium compositions, or a combination. These compositions contain a secondary, nanometer-sized precipitate phase, which is produced through processes of compositional control and ageing heat treatments. Glenn's novel materials and processes have yielded a SMA composition that produces much higher stresses than other SMAs on the commercial market. The SMARS device is composed of 1) SMA material as the actuating member; 2) a casing heater placed around the SMA member; 3) a DC or AC power source to provide current through the heater; 4) pointed tips for acute penetration into rock formations; and 5) a hand-press to reset the SMA element after each use. In the rock-splitting process, a hole equal to the diameter of the SMA element is drilled in the portion of the rock where the fracture is desired. Next, the pre-compressed SMA is inserted into the hole, and AC or DC current is applied to energize the devices heaters. Once the heater achieves the critical transformation temperature, the SMA will begin to expand within seconds. Since its expansion is constrained by the rock walls, the SMA will eventually exert up to 1500 MPa of stress, splitting the rock apart. When the current is removed and the heater cools, the SMA material returns to its pre-compressed state. At this point, the material can be recovered, so the process is repeatable after reshaping. The SMA actuating members were also designed to achieve displacement greater than the materials strain output. Glenns SMARS device provides high-powered rock fracturing that is controllable, reliable, and comparatively simple without the use of explosives, hydraulics, or chemicals.

This materials system is comprised of an Al metal matrix with high-performance SMA reinforcements. The combination of the unique matrix composition and SMA elements allow for this material system to self-repair via a two-step crack repair method. When a crack is present in the matrix material, the MMC is heated above the SMA's austenite start (As) temperature. This initiates shape recovery of the SMA, pulling the crack together as the SMA reinforcements return to their initial length. Concurrently, the increased temperature causes softening and liquefaction of the eutectic micro-constituent in the matrix, which enables the recovery of plastic strain in the matrix as well as crack filling. Combined with the crack closure force provided by the SMA reinforcements completely reverting to their original length, the MMC welds itself together and, upon cooling, results in a solidified composite able to realize its pre-cracked, original strength. The research team has demonstrated and tested the new materials. The team induced cracks in prototype materials based on Al-Si matrix with SMA (NiTi) reinforcements and demonstrated the recovery of tensile strength after healing. Data from tensile and fatigue tests of the samples before and after the fatigue crack healing shows a 91.6% healing efficiency on average under tensile conditions.