Triggering Li-ion Battery Cells with Laser Radiation

power generation and storage

Triggering Li-ion Battery Cells with Laser Radiation (MSC-TOPS-99)

Non-invasive method precisely triggers thermal runaway

Overview

Innovators at NASA Johnson Space Center have developed a high-powered infrared (IR) laser that can trigger Li-ion battery cells into thermal runaway (TR) without perforating the batterys can wall like previous methods. Inducing TR in a battery cell allows engineers to test and improve the safety performance of overheated batteries that can potentially catch fire or explode. The primary advantage of this method is the heat energy delivered by the laser can be localized to the exact target spot on the battery cell minimizing thermal biasing to adjacent cells. This laser method does not require any internal modification of the test subject cell design nor require patch heating to trigger a short-circuit. Triggering Li-ion Cells with Laser Radiation could work on any commercial battery cell design with only exterior surface treatment required, which can be done by the user.

The Technology

This technology is based upon a 120-watt IR laser is coupled to a fiber optic cable that is routed from the output of the laser into a series of focusing optics which directs energy onto a battery cell mounted to a test stand. When activated, heat from the laser penetrates the metal housing, heating the internals of the cell. At a specific temperature, the separator in the first few layers of the cell melts allowing the anode and cathode to make contact and initiates an internal short circuit. The internal short circuit then propagates throughout the battery eventually causing thermal runaway. The lower the wavelength of the laser used to produce the thermal runaway, the more heat-energy will be absorbed into the cell producing a faster result. The fiber optic cable can be terminated into a series of optics to focus the laser at a specific target, or the fiber optic cable can be stripped bare and placed next to the target to heat an isolated location. This method can also be used on a wide variety of cells, including Li-ion pouch cells, Li-ion cylindrical cells and Li-ion Large format cells. The innovation Triggering Li-ion Cells with Laser Radiation is at TRL 6 (which means a system/subsystem prototype has been demonstrated in a relevant environment) and the related patent application is now available to license and develop into a commercial product. Please note that NASA does not manufacture products itself for commercial sale.

Shown: The red arrows highlight the radial direction of TR propagation, and the yellow arrows highlight the direction of peeling and shift of the electrode assembly.

Benefits

No internal modifications required to the test cell
Helps determine response to localized internal short circuit that resembles defect-induced catastrophic field failures
Method easily replicated by battery developers for battery safety verification tests
IR laser method can test battery assemblies with minimal thermal biasing to adjacent cells

Applications

All human-occupied vehicular transport applications that require a high level of rigor in determining margins of safety (automotive, aircraft, sea vessels, spacecraft)

Download Fact Sheet as a PDF

Ask a Question

Apply to License

Technology Details

Category power generation and storage

Reference Number MSC-TOPS-99

Case Number(s) MSC-26647-1

Patent(s) (pop-up blockers must be disabled)

Papers

Tags:

power generation power storage battery cell laser radiation thermal runaway TR Li-ion battery non-invasive trigger overheated batteries heat energy patch heating short circuit commercial battery infrared laser focusing optics anode cathode pouch cell large format cell cylindrical cell field failure safety verification

Similar Results

Li-ion Cell Calorimeter

Li-ion batteries are an integral part of energy storage systems used in NASA's Exploration program, as well as many modern terrestrial industries. Innovators at the NASA Johnson Space Center wanted a better way to measure total and fractional heat response of specific types of Li-ion cells when driven into a thermal runaway condition. They developed a calorimeter with at least two chambers, one for the battery cell under test and at least one other chamber for receiving the thermal runaway ejecta debris. Both are designed to be structurally strong and thermally insulated. When the test cell is intentionally driven into thermal runaway, ejecta explodes into the ejecta chamber and is decelerated and collected. Thermal sensors are strategically placed throughout the chambers to collect thermal data during the test. Customized software analyzes the thermal data and determines key calorimeter parameters with a high degree of accuracy.

Internal Short Circuit Testing Device to Improve Battery Designs

Astronauts' lives depend on the safe performance and reliability of lithium-ion (Li-ion) batteries when they are working and living on the International Space Station. These batteries are used to power everything such as communications systems, laptop computers, and breathing devices. Their reliance on safe use of Li-ion batteries led to the research and development of a new device that can more precisely trigger internal short circuits, predict reactions, and establish safeguards through the design of the battery cells and packs. Commercial applications for this device exist as well, as millions of cell phones, laptops, and electronic drive vehicles use Li-ion batteries every day. In helping manufacturers understand why and how Li-ion batteries overheat, this technology improves testing and quality control processes. The uniqueness of this device can be attributed to its simplicity. In a particular embodiment, it is comprised of a small copper and aluminum disc, a copper puck, polyethylene or polypropylene separator, and a layer of wax as thin as the diameter of one human hair. After implantation of the device in a cell, an internal short circuit is induced by exposing the cell to higher temperatures and melting the wax, which is then wicked away by the separator, cathode, and anode, leaving the remaining metal components to come into contact and induce an internal short. Sensors record the cell's reactions. Testing the battery response to the induced internal short provides a 100% reliable testing method to safely test battery containment designs for thermal runaway. This jointly developed and patented technology is available for your company to license and develop into a commercial product. NASA does not manufacture products for commercial sale.

Carbon Fiber Sleeve Tempers Battery Thermal Runaway

The CFRP sleeve was originally intended for crewed space flight lithium-ion 18650 battery packs rated over 80 Watt-hours (Wh), which are required to be passively propagation-resistant for increased safety. Previous battery designs have addressed SWR propagation by using aluminum or steel interstitial materials to prevent SWRs from directly impacting neighboring cells, but these materials were underperforming. During testing of 18650 battery cells, it was discovered that cells over 2.6Ah in capacity can have an undesirable failure mode in which the cell wall will rupture or breach during a thermal runaway (TR) event sending heat and ejecta into an undesirable direction. TR is typically triggered when heat produced by the battery cell’s exothermic reaction leads to increased and escalating internal cell temperature, pressure, and boiling of the electrolytes. When internal cell pressure exceeds the cell’s safety relief mechanism, rupture or bursting can occur, initiating a cell-to-cell propagation that in turn results in a battery pack fire. By adding a carbon fiber reinforced polymer (CFRP) sleeve to cylindrical battery cells, a sidewall rupture (SWR) can be prevented from occurring or propagating. In initial testing, there were no SWRs of a battery cell using a CFRP sleeve. This result is believed to be due in part to a unique characteristic of CFRP sleeves compared to other materials. Carbon fiber material has a negative coefficient of expansion and accordingly shrinks when heated, while steel and aluminum expand. The shrinking of the CFRP sleeve when heated compresses the cell located within it, significantly aiding in the prevention of SWR. This technology can be implemented into other multi-physics battery safety models to guide the design of the next generation of battery cells and battery packs. This thermal runaway propagation resistant technology has a technology readiness level (TRL) of 6 (System/sub-system model or prototype demonstration in an operational environment) and is now available for patent licensing. Please note that NASA does not manufacture products itself for commercial sale.

Portable Compact Thermionic Power Cell

This compact thermionic cell (CTI) technology can be manufactured efficiently and economically using existing semiconductor fabrication technology. Its design consists of a top electron collector, separated by a vacuum gap from an electron emitter adjacent to the heat source, a thin plate of 238Pu enclosed by a thin-film insulator to protect the emitter and collector layers from overheating by the 238Pu. For a smart phone battery size, the invented compact thermionic (CTI) cell requires about 5 g maximum of 238Pu. Such small quantities are more readily available and producible, and could be reused for recycling when the CTI cell is dismantled. The emitter surface is topologically modified to have array of spikes, achievable using current semiconductor microfabrication technology. Various other geometries of emitter plates may also be used, such as an array of ridges. The smaller the emitter tips, the higher the voltage concentration.

On the right side of the instrument is a large mirror. It's called the 'Earth Shield.' When it's in space it blocks the heat from Earth that would otherwise heat up the instrument. On the left is the instrument's radiator. The black dot in the center of the frame is the cold calibration point. The Thermal Infrared Sensor (TIRS) will fly on the next Landsat satellite, the Landsat Data Continuity Mission (LDCM). TIRS was built on an accelerated schedule at NASA's Goddard Space Flight Center, Greenbelt, Md. and will now be integrated into the LDCM spacecraft at Orbital Science Corp. in Gilbert, Ariz. The Landsat Program is a series of Earth observing satellite missions jointly managed by NASA and the U.S. Geological Survey. Landsat satellites have been consistently gathering data about our planet since 1972. They continue to improve and expand this unparalleled record of Earth's changing landscapes for the benefit of all.

Silicon Oxide Coated Aluminized Polyimide Film Radiator Coating

The SiOx Coated Aluminized Polyimide Film Radiator Coating uses all the exposed surfaces on the six sides of a CubeSat as radiators. All the internal components are thermally coupled to the radiators. Waste heat from the internal components is transferred by conduction to the radiators through its aluminum structure or frame. SiOx thin film coated aluminized polyimide film is used as the radiator coating. Its total thickness is approximately 0.05 mm, which is predominately the polyimide film thickness. Polyimide film is known commercially as Kapton. The coating is bonded to the CubeSat exterior by using an acrylic transfer adhesive. SiOx Coated Aluminized Polyimide Film Radiator Coatings absorptance and emittance can be tailored to meet the component thermal requirements by altering the SiOx thickness. Since the SiOx is a thin film, altering its thickness has no significant effect on the total thickness of the radiator coating. An indium tin oxide (ITO) thin film can be added to make the coating conductive, if needed, without affecting the absorptance or emittance. This coating, with or without ITO, can be used for various CubeSat applications. By tailoring the absorptance and emittance of this coating, external MLI blankets and active heater control are eliminated. The thermal connection between heat generating components and the battery eliminates the need for a battery heater.