Activated Metal Treatment System (AMTS) for Paints

PCBs have been shown to cause cancer in animals and to have other adverse effects on immune, reproductive, nervous, and endocrine systems. Although the production of PCBs in the United States has been banned since the late 1970s, many surfaces are still coated with PCB-laden paints. The presence of PCBs in paints adds complexity and expense for disposal. Some treatment methods (e.g., use of solvents, physical removal via scraping) are capable of removing PCBs from surfaces, but these technologies create a new waste stream that must be treated. Other methods, like incineration, can destroy the PCBs but destroy the painted structure as well, preventing reuse. To address limitations with traditional abatement methods for PCBs in paints, researchers at NASAs Kennedy Space Center (KSC) and the University of Central Florida have developed the Activated Metal Treatment System (AMTS) for Paints. This innovative technology consists of a solvent solution (e.g., ethanol, d-limonene) that contains an activated zero-valent metal. AMTS is first applied to the painted surface either using spray-on techniques or wipe-on techniques. The solution then extracts the PCBs from the paint. The extracted PCBs react with the microscale activated metal and are degraded into benign by-products. This technology can be applied without removing the paint or dismantling the painted structure. In addition, the surface can be reused following treatment.

The SPEARS spikes, which are made of inexpensive plastic, are situated on rectangular support frames. Small quantities of ethanol are placed inside of each spike. The presence of the ethanol helps to drive the movement of PCBs from the sediments into the plastic. The frames are designed to be hooked together to form larger blankets that can be used to remediate larger areas. A proof-of-concept field demonstration for SPEARS was completed in 2014 at a sump pond in the Eastern U.S. Analysis at this site showed that sediment PCB-levels were remediated to below the EPA action limit of 50 milligrams per kilogram after 32 weeks using SPEARS. A second field demonstration for SPEARS was completed in September 2016 in Ontario, Canada, and a third demonstration is scheduled for 2017 as part of the Environmental Security Technology Certification Program (ESTCP). Tests are also underway to determine if SPEARS can be used to remove additional sediment contaminants, such as polycyclic aromatic hydrocarbons (PAHs) and pesticides. This technology has been exclusively licensed by ecoSPEARS {https://ecospears.com}. Contact the company for product information.

There is a significant need for an inexpensive biological approach to recover specific, targeted metals and other target materials in e-waste or other aqueous solutions that requires minimal input of resources, including energy. This invention is a method of removing or adsorbing a target substance or material, for example, a metal, non-metal toxin, dye, or small molecule drug, from solution, by functionalizing a substrate with a peptide configured to selectively bind to the target substance or material and to bind to the substrate. The substrate is fungal mycelium, and the naturally-occurring or bioengineered peptide is called a target-binding domain, which is chemically bonded to a selected solid substrate. The target chemical species binds to the target-binding domain and is removed from solution. The target can be any chemical species dissolved or suspended in the solution. Capture of the target by the substrate can isolate and allow removal of the target substance from solution, or for utilization in water filtration, or recovery of targeted chemical species from solution, particularly aqueous solution applications. The peptides used include (i) fusion peptides and/or proteins containing metal-binding domain sequence and optionally containing substrate-binding domain sequence; (ii) fusion peptides/proteins containing a metal-binding domain and a chitin-binding domain; and (iii) nucleic acids encoding fusion peptides and/or proteins containing metal-binding domain sequence. The technology enables simple scale up to a level that could be successfully implemented in an environment with limited resources, such as on a space mission or on earth in developing countries with poor access to clean water.

NASA's system was developed for smaller-scale, space-based applications. However, the technology is scalable for larger industrial and municipal water treatment applications. Implementation of the Ammonia Recovery System could significantly reduce nitrogen content from water treatment processes, meaningfully improving the quality of water. This system offers a novel way to reduce nitrogen water pollutants, while allowing for the nitrogen to be collected and reused- reducing environmental and public health risks and providing an environmentally friendly fertilizer option. NASAs environmental solutions work to sustain life on earth through space based technology The adaptable nature of this system gives it potentially broad applications in a wide variety of industries; it is particularly ideal for on-site remediation of wastewater in places like condo complexes, hotels and water parks. Current methods of ammonia recovery could not meet NASAs mission requirements, so a new process was devised to optimize for high ammonia selectivity, simplicity, low volume , low power usage and zero contaminants in the effluent. To do this, NASA designed a novel regenerable struvite-formation system for the capture of ammonia. This system has three primary functions: 1) Removal of ammonia from wastewater using a media that is highly selective for ammonia 2) Capture of the ammonia for later use (e.g., as a fertilizer) 3) Regeneration of the capture media for reuse in the system

NASA's Debris-Tolerant Valve is designed for use in machines/environments with a large quantity of airborne dust or other contaminants. Valves subjected to airborne contaminants tend to have limited lifetime due to damaged seals, bearings, and other internal components. The Debris-Tolerant Valve design addresses this problem with four core improvements over existing commercial valves that are typically used in dusty or debris-laden processes: (1) a new cylinder design that substantially decreases dust collection within the valve; (2) a rotational valve design that minimizes grinding and packing experienced by the standard ball valve; (3) the use of elastomeric seals rather than the Teflon-based seals used in existing valves which are prone to scratching and subsequent leakage; and (4) a bleed port for fluid intake that allows pressure to build slowly in the valve and eliminates the stirring of dust commonly caused by rapid inflow of air in existing valves. The operational lifetime of NASA's Debris-Tolerant Valve exceeds the lifetime of a standard commercial valve and the existing selector valve used on the ISS by 12X and 6X, respectively. NASA's valve design has fewer parts than existing valves and could be disassembled without tools, enabling easier servicing and maintenance. The Debris-Tolerant Valve is only about one-seventh (1/7) the cost of the existing ISS selector valve.