Microscale Fire Calorimeter for Combustion and Toxicity Testing

Advances in new polymers and composites along with growing industrial needs in below-ambient temperature applications have brought about the Macroflash development. Accurate thermal performance information, including effective thermal conductivity data, are needed under relevant end-use conditions. The Macroflash is a practical tool for basic testing of common materials or research evaluation of advanced materials/systems. The Macroflash can test solids, foams, or powders that are homogeneous or layered in composition. Test specimens are typically 75mm in diameter and 6mm in thickness. The cold side is maintained by liquid nitrogen at 77 K while a heater disk maintains a steady warm-side temperature from ambient up to 373 K. The steady boiloff of the liquid nitrogen provides a direct measure of the heat energy transferred through the thickness of the test specimen. Nitrogen or other gas is supplied to the instrument to establish a stable, moisture-free, ambient pressure environment. Different compression loading levels can also be conveniently applied to the test specimen as needed for accurate, field-representative thermal performance data. The Macroflash is calibrated from approximately 10 mW/m-K to 800 mW/m-K using well-characterized materials.

NASA Glenn's fully premixed burner design accomplishes the rapid mixing of the fuel and air flows while simultaneously providing backside impingement cooling to the burner face. This novel burner technology has been demonstrated to operate on hydrogen-air mixtures at pressures up to 30 bar, and at equivalence ratios (Phi) ranging from 0.15 to 5.0, but typically at equivalence ratios below 0.6 or above 2.0 for extended periods of time. It has also been demonstrated to work well with hydrogen-carbon monoxide fuel mixtures in a 1:1 mixture (by volume). The design provides a uniform zone of combustion products and temperatures, and is able to achieve complete and rapid mixing of the reactant gases over a distance as short as 5 mm, with the combustion products attaining a fully-reacted state within about 10 mm downstream of the burner face. Effectiveness of the mixing is not dependent on the use of hydrogen gas, therefore the system works well for other gaseous fuels such as methane, propane, or natural gas, in a fully premixed mode. The design of the Glenn's burner is simple and straightforward to manufacture using conventional techniques. The modular design of the burner lends itself to scalability for larger power output applications. This burner is simple to operate and is robust for use in an industrial setting such as low-emissions stationary gas turbine engine, or for aircraft gas turbine engines.

In order to maintain the low cost, simplicity, and quick turnaround of cold-flow testing while improving accuracy, NASA evaluated unconventional gases for use as simulants. During such evaluations, NASA discovered that by adjusting stagnation temperature, the isentropic exponent of ethane can be tuned to approximate those of common rocket propellants (e.g., hydrogen, hypergols, alcohols, and hydrocarbons). Furthermore, due to ethanes high auto-ignition temperature and resistance to condensation, tuned ethane enables testing of expansion ratios much larger than conventional inert-gas testing. To leverage this discovery, NASA developed a hardware-based system to treat ethane and obtain nozzle chamber conditions that match the appropriate aerodynamics for a specific test. The system, named HYPERFIRE, works in the following manner. Liquid ethane is transferred to a piston-style run tank, where it is pressurized. Then, the ethane is run through two insulated pebble beds where it is heated, vaporized, and stabilized. Finally, the treated ethane is transferred from the second pebble bed to a small thrust takeout structure, and through the test article. Control of valves and regulators is managed by an onboard computer, accessed via a LabVIEW™ interface. The system is mounted on a hurricane-resistant steel frame to enable transportation via forklift. Heated ethane reproduces the aerodynamics of combustion products at low temperatures relative to alternative testing methods. Thus, test articles can be manufactured using low-cost, low temperature rated, transparent materials (e.g., acrylic). In addition to reducing testing cost, this grants optical access to internal flowfields, enabling advanced diagnostic techniques (e.g., Schlieren imaging, particle image velocimetry) not possible with hot-fire testing and less meaningful with conventional cold-flow testing.

Traditional cargo fire detection systems rely on fixed thresholds, such as a specific temperature, to trigger alarms. However, these static approaches are prone to false positives and may miss slow-developing fires. This patented system introduces a novel method that evaluates sensor data dynamically, based on both spatial location and temporal evolution. Temperature sensors distributed throughout the cargo compartment generate continuous data streams which are analyzed over defined time windows. The system compares sensor values across locations and over time, identifying anomalies that indicate real fire events rather than harmless fluctuations. Configurable parameters allow operators to adapt detection sensitivity to different operational conditions, cargo types, and environmental variables. This method supports early detection of fires in Class C cargo compartments, including those inaccessible during flight. It is designed to integrate with aircraft health monitoring and fire suppression systems, and it can be deployed in both new aircraft designs and as a retrofit to existing platforms equipped with sensor arrays.

The low-temperature oxidation catalyst technology employs a novel catalyst formulation, termed platinized tin oxide (Pt/SnOx). The catalysts can be used on silica gel and cordierite catalyst supports, and the latest developments provide sprayable formulations for use on a range of support types and shapes. Originally developed for removal of CO, the catalyst has also proven effective for removal of formaldehyde and other lightweight hydrocarbons. NASA researchers have also extended the capability to include reduction of NOx as well as developed advanced chemistries that stabilized the catalyst for automotive catalytic converters via the engineered addition of other functional components. These catalyst formulations operate at elevated temperatures and have performed above the EPA exhaust standards for well beyond 25,000 miles. In addition, the catalyst can be used in diesel engines because of its ability to operate over an increased temperature range. For use as a gas sensor, the technology takes advantage of the exothermic nature of the catalytic reaction to detect formaldehyde, CO, or hydrocarbons, with the heat being produced proportional to the amount of analyte present.