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Materials and Coatings
catalyst
Low-Temperature Oxidation/ Reduction Catalysts
The low-temperature oxidation catalyst technology employs a novel catalyst formulation, termed platinized tin oxide (Pt/SnOx). The catalysts can be used on silica gel and cordierite catalyst supports, and the latest developments provide sprayable formulations for use on a range of support types and shapes. Originally developed for removal of CO, the catalyst has also proven effective for removal of formaldehyde and other lightweight hydrocarbons. NASA researchers have also extended the capability to include reduction of NOx as well as developed advanced chemistries that stabilized the catalyst for automotive catalytic converters via the engineered addition of other functional components. These catalyst formulations operate at elevated temperatures and have performed above the EPA exhaust standards for well beyond 25,000 miles. In addition, the catalyst can be used in diesel engines because of its ability to operate over an increased temperature range. For use as a gas sensor, the technology takes advantage of the exothermic nature of the catalytic reaction to detect formaldehyde, CO, or hydrocarbons, with the heat being produced proportional to the amount of analyte present.
materials and coatings
Testing of Materials
Adaptive Thermal Management System
Efficient thermal management has long been an issue in both commercial systems and in the extreme environments of space. In space exploration and habitation, significant challenges are experienced in providing fluid support systems such as cryogenic storage, life support, and habitats; or thermal control systems for launch vehicle protection, environmental heat management, or electronic instruments. Furthermore, these systems operate in dynamic, transient modes and often under extremes of temperature or pressure. The current technical requirements associated with the thermal management of these systems result in control issues as well as significant life-cycle costs. To combat these issues, the Adaptive Thermal Management System (ATMS) was developed to help provide the capability for tanks, structural walls, or composite substrate materials to switch functionality (conductive or insulative) depending on environmental conditions or applied stimuli. As a result, the ATMS provides the ability to adapt between both heating and cooling modes within a single system. For example, shape memory alloy (SMA) elements are used to actuate at certain design temperatures to create a conductive bridge between two metal plates allowing broad-area heat rejection from the hotter surface. Upon cooling to the lower design set-point, the SMA elements return to their original shapes, thereby breaking the conductive path and returning the system to its overall insulative state. This technology has the potential to be applied to any system that would have the need for a self-regulating thermal management system that allows for heat transfer from one side to another.
instrumentation
Cryostat-500 (disassembled)
Cryostat-500
The Cryostat-500 provides laboratory measurement of the steady-state thermal transmission properties of thermal insulation systems under conditions below ambient temperature. Liquid nitrogen is used as a direct measure of the energy going through the test specimen. Thermal insulation systems may be composed of one or more materials that may be homogeneous or non-homogeneous at boundary conditions from 77 K to 373 K and in environments from high vacuum (10E-7 torr) to ambient pressure (10E+3 torr). The Cryostat-500 provides a much wider range of thermal performance and covers the full range of environmental conditions for applications below ambient temperature. The instrument has been proven through extensive testing of foams, composite panels, multilayer insulation (MLI) systems, aerogel blankets, fiberglass, and many other types of materials. Both the quality and quantity of the thermal performance data for insulation materials and systems have increased even as the process and method has become more time efficient and cost effective. Further guidelines on the test method and equipment for the Cryostat-500 are given in ASTM C1774, Annex A3.
mechanical and fluid systems
front image
Variable-Aperture Reciprocating Reed (VARR) Valve
The VARR valve has been designed to provide a variable-size aperture that proportionately changes in relation to gas flow demand. When the pressure delta between two chambers is low, the effective aperture cross-sectional area is small, while at high delta pressure the effective aperture cross-sectional area is large. This variable aperture prevents overly restricted gas flow. As shown in the drawing below, gas flow through the VARR valve is not one way. Gas flow can traverse through the device in a back-and-forth reversing flow manner or be used in a single flow direction manner. The contour shapes and spacing can be set to create a linear delta pressure vs. flow rate or other pressure functions not enabled by current standard orifices. Also, the device can be tuned to operate as a flow meter over an extremely large flow range as compared to fixed-orifice meters. As a meter, the device is capable of matching or exceeding the turbine meter ratio of 150:1 without possessing the many mechanical failure modes associated with turbine bearings, blades, and friction, etc.
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