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The Aerofoam composites have superior thermal and acoustic insulation properties when compared to conventional polyimide foams. In addition, they provide greater structural integrity than the fragile aerogel materials can provide independently. In general, polymer foams can provide excellent thermal insulation, and polyimide foams have the additional advantage of excellent high-temperature behavior and flame resistance compared to other polymer systems (they do not burn or release noxious chemicals). Incorporating aerogel material into the polyimide foam as described by this technology creates a composite that has been demonstrated to provide additional performance gains, including 25% lower thermal conductivity with no compromise of the structural integrity and high-temperature behavior of the base polyimide foam. The structural properties of Aerofoam are variable based on its formulation, and it can be used in numerous rigid and flexible foams of varying densities. Aerofoam has a number of potential commercial applications, including construction, consumer appliances, transportation, electronics, healthcare, and industrial equipment. In addition, these high-performance materials may prove useful in applications that require insulation that can withstand harsh environments, including process piping, tanks for transporting and storing hot or cold fluids, ship and boat building, and aerospace applications.

Researchers at JPL have developed, built, and tested an innovative heat exchanger that offers reduced thermal expansion, increased structural strength, low pressure drop, and improved thermal performance while lowering the weight associated with typical heat exchangers. This innovation would benefit the commercial thermoelectric generator, aircraft, and industrial processing (i.e., glass, steel, petrochemical, cement, aluminum) industries by improving energy management/efficiency, reducing carbon dioxide emissions, and increasing system durability due to the reduced stress from thermal expansion. <b>The Problem</b> Thermoelectric generator systems require high-performance hot-side and cold-side heat exchangers to provide the temperature differential needed to transfer thermal energy while withstanding temperatures up to 650 &#176;C. Because the hot-side heat exchangers must have a high heat flux, they are often made of metals such as stainless steel or Inconel^&#174; alloys. Although these materials can operate at high temperatures, resist corrosion, and are chemically stable, they also have several drawbacks: (1) Their lower thermal conductivity negatively affects their thermal performance. (2) Their higher thermal expansion leads to stresses that compromise system structural integrity. (3) Their high mass/volume reduces the power density of generator systems into which they are integrated. As a result, they are difficult to integrate into viable energy recovery systems. They also make the systems unreliable, non-durable, and susceptible to failures caused by thermal-structural expansion. <b>The Solution</b> JPL researchers chose to replace the metal in traditional heat exchangers with graphite, which offers an improved conductivity-to-density ratio in thermal applications as well as a low coefficient of thermal expansion. In addition, they used a mini-channel design to further increase thermal performance. Combining more advanced materials with the innovative thermal design has yielded significant improvements in performance. For example, a 200-cm³, 128-g version of JPL's exchanger successfully transported 1,100 W from exhaust at nearly 550 &#176;C with approximately 20 W/cm² thermal flux and a pressure drop of only 0.066 psi. JPL's technology combines lightweight, high-strength graphite material with a mini-channel design that offers high thermal performance. Further development and testing are underway. <em>Inconel is a registered trademark of Special Materials Corporation.</em>

The new composite developed by NASA incorporates PGS and CNTs to enhance its thermal conductivity while preserving the mechanical properties of the underlying carbon fiber polymer composite. NASA has also improved the composite manufacturing process to ensure better thermal conductivity not only on the surface, but also through the thickness of the material. This was achieved by adding perforations that enable the additives to spread through the composite. The process for developing this innovative, highly thermally conductive hybrid carbon fiber polymer composite involves several steps. Firstly, a CNT-doped polymer resin is prepared to improve the matrix's thermal conductivity, which is then infused into a carbon fiber fabric. Secondly, PGS is treated to enhance its mechanical interface with the composite. Thirdly, perforation is done on the pyrolytic graphite sheet to improve the thermal conductivity through the thickness of the material by allowing CNT-doped resin to flow and better interlaminar mechanical strength. Finally, the layup of PGS and CNT-CF polymer is optimized. Initial testing of the composite has shown significant increases in thermal conductivity compared to typical carbon fiber composites, with a more than tenfold increase. The composite also has higher thermal conductivity than aluminum alloys, with more than twice the thermal conductivity of the Aluminum 6061 typically used in the aerospace industry. For this new material, NASA has completed a proof-of-concept demonstration and work continues to use the material in a heat exchanger system and further characterize the properties including longevity and radiation impact analysis.

Going farther, faster and hotter in space means innovating how NASA constructs the materials used for heat shields. For HEEET, this results in the use of dual-layer, three-dimensional, woven materials capable of reducing entry loads and lowering the mass of heat shields by up to 40%. The outer layer, exposed to a harsh environment during atmospheric entry, consists of a fine, dense weave using carbon yarns. The inner layer is a low-density, thermally insulating weave consisting of a special yarn that blends together carbon and flame-resistant phenolic materials. Heat shield designers can adjust the thickness of the inner layer to keep temperatures low enough to protect against the extreme heat of entering an atmosphere, allowing the heat shield to be bonded onto the structure of the spacecraft itself. The outer and inner layers are woven together in three dimensions, mechanically interlocking them so they cannot come apart. To create this material, manufacturers employ a 3-D weaving process that is similar to that used to weave a 2-D cloth or a rug. For HEEET, computer-controlled looms precisely place the yarns to make this kind of complex three-dimensional weave possible. The materials are woven into flat panels that are formed to fit the shape of the capsule forebody. Then the panels are infused with a low-density version of phenolic material that holds the yarns together and fills the space between them in the weave, resulting in a sturdy final structure. As the size of each finished piece of HEEET material is limited by the size of the loom used to weave the material, the HEEET heat shield is made out of a series of tiles. At the points where each tile connects, the gaps are filled through inventive designs to bond the tiles together.

The technology utilizes photopolymer droplets (invisible to the digital radiograph) with embedded radiopaque fragments to create randomized fingerprints on battery samples. The droplets are deposited using a jig (see figure on right) that precisely positions samples. Then, at different points during battery R&D testing or use, digital radiography imaging with micron-level resolution can be performed. The high-resolution imaging required to detect dendrite formation requires images to be collected in multiple “tiles” as shown below. The randomized fingerprints uniquely identify relative positioning of these tiles, allowing rapid assembly of composite high-resolution images from multiple tiles. This same composite creation process can be used for images taken at a series of points in time during testing, and background subtraction can be applied to efficiently compare how the battery is changing over successive charge/discharge cycles to identify dendrite formation. This inspection technique is proven effective for thin-film pouch cell prototypes at NASA, and it works well at the lowest available x-ray energy level (limiting impact on the samples). The Fingerprinting for Rapid Battery Inspection technology is available for patent licensing.

Sometimes called white graphite, affordable and plentiful hBN possesses the same kind of layered molecular structure as graphite. In graphite, this structure has allowed next-generation nanomaterials like carbon nanotubes and graphene to be produced. With hBN, however, the process of converting the substance into boron nitride nanotubes (BNNT) has been too difficult to yield commercial quantities. Glenn innovators have created several new methods that could enable greater adoption of this unique nanomaterial. In the initial stage, the starter reactant is mixed with a selected set of chemicals (a metal chloride, for example) and an activation agent (such as sodium fluoride). This mixture causes hBN to become less resistant to intercalation. The intercalated product can then be exfoliated by heating the material in air, and giving the material a final rinse with a liquid-phase ferric chloride salt to dissolve any embedded impurities without damaging its internal structure. These efficiently exfoliated nanomaterials can be used to form advanced composite materials (e.g., layered with aluminum oxide to form hBN/alumina ceramic composites). Nanomaterials fabricated from hBN can also take advantage of the material's unique combination of being an electrical insulator with high thermal conductivity for applications ranging from microelectronics to energy harvesting. Glenn's innovations have enabled a significantly improved matrix composite material with the potential to make a significant impact on the commercial materials market.

This new technology applies NASA engineering to a FLIR Systems Boson® Model No. 640 to enable a robust IR camera for use in space and other extreme applications. Enhancements to the standard Boson® platform include a ruggedized housing, connector, and interface. The Boson® is a COTS small, uncooled, IR camera based on microbolometer technology and operates in the long-wave infrared (LWIR) portion of the IR spectrum. It is available with several lens configurations. NASA's modifications allow the IR camera to survive launch conditions and improve heat removal for space-based (vacuum) operation. The design includes a custom housing to secure the camera core along with a lens clamp to maintain a tight lens-core connection during high vibration launch conditions. The housing also provides additional conductive cooling for the camera components allowing operation in a vacuum environment. A custom printed circuit board (PCB) in the housing allows for a USB connection using a military standard (MIL-STD) miniaturized locking connector instead of the standard USB type C connector. The system maintains the USB standard protocol for easy compatibility and "plug-and-play" operation.

This NASA technology transforms a conventional infrared (IR) imaging system into a multi-wavelength imaging pyrometer using a tunable optical filter. The actively tunable optical filter is based on an exotic phase-change material (PCM) which exhibits a large reversible refractive index shift through an applied energetic stimulus. This change is non-volatile, and no additional energy is required to maintain its state once set. The filter is placed between the scene and the imaging sensor and switched between user selected center-wavelengths to create a series of single-wavelength, monochromatic, two-dimensional images. At the pixel level, the intensity values of these monochromatic images represent the wavelength-dependent, blackbody energy emitted by the object due to its temperature. Ratioing the measured spectral irradiance for each wavelength yields emissivity-independent temperature data at each pixel. The filters Center Wavelength (CWL) and Full Width Half Maximum (FWHM), which are related to the quality factor (Q) of the filter, are actively tunable on the order of nanoseconds-microseconds (GHz-MHz). This behavior is electronically controlled and can be operated time-sequentially (on a nanosecond time scale) in the control electronics, a capability not possible with conventional optical filtering technologies.

The CFRP sleeve was originally intended for crewed space flight lithium-ion 18650 battery packs rated over 80 Watt-hours (Wh), which are required to be passively propagation-resistant for increased safety. Previous battery designs have addressed SWR propagation by using aluminum or steel interstitial materials to prevent SWRs from directly impacting neighboring cells, but these materials were underperforming. During testing of 18650 battery cells, it was discovered that cells over 2.6Ah in capacity can have an undesirable failure mode in which the cell wall will rupture or breach during a thermal runaway (TR) event sending heat and ejecta into an undesirable direction. TR is typically triggered when heat produced by the battery cell’s exothermic reaction leads to increased and escalating internal cell temperature, pressure, and boiling of the electrolytes. When internal cell pressure exceeds the cell’s safety relief mechanism, rupture or bursting can occur, initiating a cell-to-cell propagation that in turn results in a battery pack fire. By adding a carbon fiber reinforced polymer (CFRP) sleeve to cylindrical battery cells, a sidewall rupture (SWR) can be prevented from occurring or propagating. In initial testing, there were no SWRs of a battery cell using a CFRP sleeve. This result is believed to be due in part to a unique characteristic of CFRP sleeves compared to other materials. Carbon fiber material has a negative coefficient of expansion and accordingly shrinks when heated, while steel and aluminum expand. The shrinking of the CFRP sleeve when heated compresses the cell located within it, significantly aiding in the prevention of SWR. This technology can be implemented into other multi-physics battery safety models to guide the design of the next generation of battery cells and battery packs. This thermal runaway propagation resistant technology has a technology readiness level (TRL) of 6 (System/sub-system model or prototype demonstration in an operational environment) and is now available for patent licensing. Please note that NASA does not manufacture products itself for commercial sale.

The advent of additive manufacturing makes available new and innovative integrated thermal management systems, including integrating an oscillating Heat Pipe (OHP) into the leading edge of a hypersonic vehicle for rapid dissipation of large quantities of heat. OHPs have interconnected capillary channels filled with a working fluid that forms a train of liquid plugs and vapor bubbles to facilitate rapid heat transfer. Multiple additive manufacturing techniques may be used, including powder bed fusion, binder jetting, metal material extrusion, directed energy deposit, sheet lamination, ultrasonic, and electrochemical techniques. These high performance OHPs can be made with materials such as Refractory High Entropy Alloys (RHEAs) that can withstand high temperature applications. The structure of the OHP can be integrated into the constructed leading edge. The benefits include a heat transport capacity of 10 to 100 times greater than before. Integrated OHPs avoid the bends or welds in traditional heat pipes, especially at the locations where the highest thermal stresses might cause thermal-structural failure of a leading edge. Alternating the diameters of the OHP channels alleviate start-up issues typically found in liquid metal oscillating heat pipe designs in high temperature applications by aiding in the instigation of a circulating flow due to multiple forces acting upon the working fluid.