Puncture-healing Engineered Polymer Blends

This innovation utilizes a tri-layered structure, comprised of solid plastic front and back layers sandwiching a viscous, reactive liquid middle layer. Combined, this system provides rapid self-healing following high velocity ballistic penetrations. Self-healing in the front and back layers occurs when the puncture event creates a melt state in the polymer materials and the materials melt elasticity snaps back and closes the hole. The viscous middle layer augments the self-healing properties of the other layers by flowing into the gap created by a ballistic puncture and concurrently solidifying due to the presence of oxygen. Thus, this innovation has two tiers of self-healing: a puncture-healing mechanism triggered by the projectile and a second mechanism triggered by the presence of oxygen.

A composite fabrication process cycle was developed from composite precursor materials developed at LaRC to fabricate composite laminates. The precursor material is a pre-impregnated unidirectional carbon fiber preform, or prepreg. In the pre-pregging process, the high strength, structural reinforcing carbon fiber is wetted by a solution containing a self-healing polymer. The resulting material is of aerospace quality and exhibits a significant decrease of internal damage following impacts tests (using ASTM D 7137 standard).

To replicate flat delaminations/disbonds in composites/bonded structures, solid monoliths of aerogel are fabricated to very thin tabs (greater than 1 mm). The thin tabs are laid on a ply layer during layup of the composite at a desired ply depth and spatial location. The rest of the composite is constructed and then cured in an autoclave. After curing the aerogel insert will completely mimic a thin air gap between the ply layers only at the area it was located. The aerogel insert will be a large acoustic impedance mismatch in the composites, meaning it will respond like a delamination in all acoustic-based measurements. And because they are very good insulators, they will also respond like a delamination in thermal-based inspections. A particulate aerogel based method can be used to represent porosity.

NASA used three strategies to develop a family of modified epoxy resins for use in an improved composite layup configuration. By tailoring molecular structures, incorporating secondary additives, and adjusting composite architecture, NASA has produced fiber-reinforced polymer composites that suppress viscoelastic creep and relaxation. Specifically the three strategies were: (1) Controlling the cross-linking density using reactive functional groups and selecting appropriate monomers with stoichiometry adjustments. A higher stoichiometric ratio is responsible for reduced relaxation compared to a lower ratio (resulting in 26% relaxation after 1 year vs. 49%). (2) Increase the steric hindrance by reducing free volume and enhancing intermolecular interaction. This involved the preparation of two different reactive low molecular weight oligomers The best epoxy resin created was from the VCD/HAA additives with 15-17% relaxation; DEGBA/HAA had 22-25% relaxation. (3) Optimizing different carbon fiber layup configurations for woven structures made into a highly stiff boom, highly flexible boom, a small size boom, and a large size boom application. The best configuration was that of a highly stiff boom with 4-5% relaxation. Other carbon fiber layup configurations had 16-30% relaxation. As shown in the figure below, NASA tested the relaxed composite using an accelerated test with variable temperatures.

This technology enables the fabrication of co-cured structures without the need for an autoclave or oven large enough to contain the full-scale structure. Instead, sub-components can be prepared in a less expensive, smaller autoclave or oven with co-cure plys applied to the faying surfaces. A continuous, assembled structure can be prepared using a subsequent curing process in a heated press. The co-cured structures can be designed to meet FAA certification criteria for composite structures because no adhesive bond or mechanical fasteners are needed. The structure can be treated as a single, joint-free component.