Healable Carbon Fiber Reinforced Composites

The method chemically introduces mechanically sensitive chemical groups into the structure of a resin. By introducing mechanoresponsive functional groups to a polymer, it is possible to induce self-healing through the transformation of such chemical groups to where mechanical properties of a structure are almost completely restored. The forces imparted by a damage event can therefore be used to enable healing or repair of the structure.

Designers are constantly seeking to improve the power-to-weight ratio of components in rotorcraft and other flight vehicles. One approach has involved using lightweight carbon fiber composite materials to replace gear web portions and other components that are typically made from steel. The problem with using fiber composite materials comes when more complex shapes are required. To create thickness variation and other accommodations for complex shapes, manufacturers can stack cut continuous fiber plies and/or form short, fiber-reinforced composite material to the desired shape. Unfortunately, these methods leave cut fiber ends within the structure, which often become initial sites for high cycle fatigue damage in high speed, high power density applications. Glenn's new method tackles this problem with one of three approaches. The first approach is applicable to gears that are planar in shape and have a single hub and a single rim. The hub and web sections of the gear are made as an integrated structure with decreased thickness from the hub inner diameter to the web outer diameter. The thickness variation is accomplished using multiple layers of continuous fiber composite material formed to specific shapes and separated by filler materials. The second approach is applicable to gears that have an extended gear body in the axial direction rather than a simple planar structure. In this approach, the gear body is made using multiple layers of continuous fiber composite material in the shape of a solid of revolution. The third approach is a power transfer assembly made by combining approaches one and two. With any of these three approaches, the material can be tailored to the structure by the properties of fibers used, the number of fiber layers used, and the location of the fibers relative to the neutral axis of the structure. Glenn's innovation opens the door for carbon fiber composite materials to be used for many applications for which they were previously unsuited.

This innovation utilizes a tri-layered structure, comprised of solid plastic front and back layers sandwiching a viscous, reactive liquid middle layer. Combined, this system provides rapid self-healing following high velocity ballistic penetrations. Self-healing in the front and back layers occurs when the puncture event creates a melt state in the polymer materials and the materials melt elasticity snaps back and closes the hole. The viscous middle layer augments the self-healing properties of the other layers by flowing into the gap created by a ballistic puncture and concurrently solidifying due to the presence of oxygen. Thus, this innovation has two tiers of self-healing: a puncture-healing mechanism triggered by the projectile and a second mechanism triggered by the presence of oxygen.

Formation of the inventive polymer composite matrix begins by growing carbon nanotubes directly on a veil substrate. The carbon nanotubes are grown from both sides of a non woven carbon fiber mat. The carbon nanotubes can be single or multi walled and can be grown to predetermined lengths. The veiled substrate is positioned between carbon fiber/ polymer prepreg layers such that the carbon nanotubes protrude into the reinforcement layers. The polymer composite matrix formed following curing of the resin exhibits improved interlaminar strength, fracture toughness and impact resistance. Because of the thinness of the veil layer, electricity can pass from conductive carbon nanotubes on one side of the veil to conductive carbon nanotubes on the other side of the veil. Electricity can also pass between two veils intercalated into the same reinforcement layer when the length of the nanotubes is sufficiently long enough to provide overlap within the reinforcement layers.

Puncture healing melt blends were developed by melt blending self-healing polymers with non self-healing polymeric materials. The self-healing polymeric materials consisted of Surlyn&#174 8940, Affinity&#8482 EG 8200 G, and poly(butadiene)-graft-poly(methyl acrylate-co-acrylonitrile) or Barex&#174 210 IN. The non-self-healing polymeric materials consisted of poly(ether ether ketone) (PEEK), LaRC phenyl ethynyl terminated imide 330 (LaRC PETI 330), and Raptor Resins Bismaleimide-1 (BMI-1). Puncture healing blends were also prepared with chopped glass and chopped carbon fibers. The overall goal was to develop a product with superior properties relative to either of the starting materials. The melt blends were prepared in varying compositions to optimize desired properties of the resulting matrix. Ballistic testing was conducted to determine the self-healing characteristics of several developmental polymers subjected to micrometeoroid type damage.