Vertically Aligned Carbon Nanotubes

NASA's new material is a toughened triaxial braid made from ductile carbon nanotube (CNT) yarn hybridized with carbon fiber, which is ultimately used as reinforcement material to make toughened polymer matrix composites. The CNT yarn component of the reinforcement is solely responsible for adding toughness, while the processes used to optimize the fiber braiding parameters and tensile properties of the carbon fiber-CNT yarn hybrid tow material determine the overall improvement in tensile strength for resin impregnated fiber tows. Bundles of continuous carbon nanotube yarns are combined with a similar format of carbon fiber, yielding an easily scalable process. Advantages of the material include reduced cost by eliminating use of toughening agents, increased ability to conform to highly complex geometries, greater environmental stability compared to aramid fiber reinforcements such as Kevlar, and possibly decreased density. Many hybrid reinforcements exhibit interfacial compatibility issues, which could lead to premature failure via crack propagation at the polymer matrix interface. In contrast, chemical similarities between the CNT yarn and carbon fiber constituents impart NASA's hybrid reinforcement material with excellent interfacial compatibility. Potential applications include aerospace components, composite pressure vessels, wind turbine blades, automotive components, prosthetics, sporting equipment, construction reinforcement material, and other use-cases where strength-to-weight ratio is of utmost importance.

Carbon nanotubes (CNTs) show promise for multifunctional materials for a range of applications due to their outstanding combination of mechanical, electrical and thermal properties. However, these promising mechanical properties have not translated well to CNT nanocomposites fabricated by conventional methods due to the weak load transfer between tubes or tube bundles. In this invention, the carbon nanotube forms such as sheets and yarns were modified by in-situ polymerization with polyaniline, a -conjugated conductive polymer. The resulting CNT nanocomposites were subsequently post-processed to improve mechanical properties by hot pressing and carbonization. A significant improvement of mechanical properties of the polyaniline/carbon nanotube nanocomposites was achieved through a combination of stretching, polymerization, hot pressing, and carbonization.

NASA's new calibration system is a proprietary method to quickly design and make predictable and repeatable gap-and-overlap defects when employing AFP. The system creates defects within the course of layup with known sizes, geometries, and locations. Using this defect-creation technique, one can now accurately quantify the ability to detect defects on inspection systems, perform accurate risk assessments, and calibrate in-situ inspection equipment to specific materials. The equipment that makes the defects can be efficiently and inexpensively 3D printed. This technique is currently being used to successfully calibrate NASA's in situ inspection system for their AFP equipment. AFP is experiencing increasing adoption in aerospace, automotive, and other industries that leverage large-scale advanced composite components. NASA's new AFP calibration system could be very useful to companies that develop and manufacture AFP machines or AFP machine inspection equipment to improve the quality of their products in a provable manner. Furthermore, users of AFP machines may find value in the tool for creating their own calibration standards.

Deployable space structures often rely upon telescoping or folding structures that either must be manually deployed or deployed by attached motors. These structures are often made from heavier (relative to carbon fiber composites) metals to provide enough strength to support a load. As such, there is a need for in-space structures that are lightweight, can be packaged compactly, and can be deployed easily. The composite material developed here does not require high temperature baking to cure the polymer, rather relying on UV light to solidify the polymer component. The composite is then included into origami-based structures that can fold and deploy using the polymer shape memory effect. The composite is first trained to assume the deployed structural shape when heated; it is then folded like origami and frozen into the packaged shape for storage and launch. Combining the composite material with the origami-inspired design leads to high strength structures (can hold at least 600 kg on Earth). To date, a ~5-inch prototype structural bar has been produced using the UV-curable composite and further development is on-going at NASA Langley. The deployable origami composite structures are at technology readiness level (TRL) 4 (component and/or breadboard validation in laboratory environment) and are available for patent licensing.

CMCs are a game-changer for a number of applications because of their lighter weight, higher temperature capability, and resistance to oxidation. It has been estimated that aircraft designs relying on CMCs can decrease fuel consumption by 10% by 2020. EBCs are used to protect CMCs from water vapor and other corrosive gases inside engines and other extreme environments. The current state of the art for EBCS features a silicon bond coat that is not viable beyond its melting point of 1482°C. By contrast, Glenn's EBCs have demonstrated a steam oxidation life of at least 500 hours at 1482°C, making them ideal durable coatings for next-generation CMCs. These EBCs are slurries, with either a mullite-based bond coat or a rare earth disilicate-based bond coat comprising at least three and two layers, respectively. Mullite is often used as a refractory material for furnaces, reactors, etc. because of its high melting point (1840°C). Rare earth disilicates also have high melting points (~1800°C). These bond coats can be fabricated by preparing a mixture of a coating material, a primary sintering aid, at least one secondary sintering aid, and a solvent. The mixture is then processed (e.g., in a milling media) to form a slurry that can be deposited to a CMC substrate. The sintering aids have two primary functions: 1) densifying deposited slurry by generating liquid phases via reactions with the coating material and other sintering aids, so that the liquid fills gaps between particles of coated material; 2) enhancing bonding and performance of the coating by generating reaction products that enhance those qualities. One great advantage of this EBC is that it can be fabricated via various low-cost methods - including dipping, spinning, spin-dipping, painting, and spraying - in addition to plasma-spraying. Glenn's innovation rises to meet the need for a new class of EBCs that can keep up with CMCs' increasing ability to withstand higher temperatures and stresses than ever before.