Metallic Junction Thermoelectric (MJTE) Generator

Solid state power conversion devices, such as thermoelectrics, depend upon temperature gradients for their operation. For example, aeronautic gas turbine engines maintain the necessary temperature gradients throughout their systems due to the enthalpic processes of combustion, which offers the possibility of generating electrical power for use in primary and secondary electrical systems in the aircraft. However, until now thermoelectric materials have not been able to withstand the combination of high temperatures and oxidative environments present in gas turbine engines. Glenn's innovation overcomes these limitations by using a doped oxide pyrochlore (crystal compound) semiconductor as the thermoelectric material. The material has a low thermal conductivity, which allows it to maintain a thermal gradient and sufficient electrical conductivity to produce an electromotive force. The pyrochlore allows the thermoelectric material to be present within a gas turbine engine, converting heat directly into electricity and functioning at high temperatures without oxidizing in air. Glenn's innovative thermoelectric material permits the benefits of solid-state power conversion devices to improve fuel efficiencies for a broader range of applications than has ever been possible. This innovation is in the early stages of development, and Glenn welcomes opportunities for co-development.

This compact thermionic cell (CTI) technology can be manufactured efficiently and economically using existing semiconductor fabrication technology. Its design consists of a top electron collector, separated by a vacuum gap from an electron emitter adjacent to the heat source, a thin plate of 238Pu enclosed by a thin-film insulator to protect the emitter and collector layers from overheating by the 238Pu. For a smart phone battery size, the invented compact thermionic (CTI) cell requires about 5 g maximum of 238Pu. Such small quantities are more readily available and producible, and could be reused for recycling when the CTI cell is dismantled. The emitter surface is topologically modified to have array of spikes, achievable using current semiconductor microfabrication technology. Various other geometries of emitter plates may also be used, such as an array of ridges. The smaller the emitter tips, the higher the voltage concentration.

The thin film sensor’s principal advantage lies in its potential to take high frequency temperature measurements from the surface of a reentering spacecraft while simultaneously withstanding the high temperature and oxidizing environment encountered. This data provides engineers with operational phase measurements used to refine the spacecraft’s operational envelope and track flight hardware behavior in addition to providing high frequency temperature measurements that can inform the physics of a boundary layer. Mismatches in coefficients of thermal expansion (CTE) are expected in TPS-based sensor applications because the metallic materials used for temperature sensing have thermal expansion rates that differ from the rates of the substrate and coating materials in the TPS. At high temperatures during reentry, this mismatch in CTE can create a significant strain differential between the metallic sensor, sensor leads, and the materials to which the sensor and leads are bonded. High frequency response temperature measurements on the surface of entry spacecraft are not currently possible above ~700 F with existing measurement capabilities. This shortcoming is primarily due to the need for robust sensor behavior at temperatures of several thousand degrees F. The sensor design of this technology preserves the integrity of sensor components while enhancing its high temperature functionality. The thin film temperature sensor has a technology readiness level (TRL) 5 (Component and/or breadboard validation in relevant environment) and is now available for patent licensing. Please note that NASA does not manufacture products itself for commercial sale.

By varying the number, type, orientation and functionality of various solar panel materials, a diverse family of devices can be constructed that can be tailored for many operational concepts. Various solar panel designs can be constructed that include active, cooling, and solar absorbance layers with tailored characteristics. This flexibility is achieved by arranging multiple solar absorbance layers that are coupled to polymer composite solar absorbance layers. The polymer composite can contain metal salts, oxides and/or carbon nanotubes as needed for various applications. The polymer can be chosen for flexibility or stiffness characteristics as needed by the designer. Configurations can include cooling layers with zinc oxides, indium oxides, and/or carbon nanotubes coupled between active layers. The carbon nanotubes can be aligned in a particular direction of the second cooling layer to achieve a heat flow bias. The cooling layer may be grooved to match other functional layers to increase the surface area for heat transfer.

This technology is a new sensor made up of dielectric materials tuned to accurately measure a variable and wide range of temperatures. The sensor is wireless and is powered by an external magnetic field. As the temperature changes, the dielectric material changes its signature magnetic response and the change is detected by a magnetic field response sensor. Applications for this technology are temperature sensors for non-conductive surfaces where the conditions or operations require a robust and wireless sensor.