Oxide Dispersion Strengthened Medium Entropy Alloy

The manufacturing process, building on techniques showcased in LEW-TOPS-151, employs a novel acoustic mixing technique to coat spherical C103 powder particles with a uniform distribution of sub-200 nanometer yttria particles. During laser powder bed fusion additive manufacturing, layer-by-layer remelting disperses these yttria particles uniformly throughout the component microstructure. This eliminates the expensive, time-consuming mechanical alloying steps traditionally required for ODS alloys while enabling near-net-shape fabrication of complex geometries. Performance testing demonstrates substantial improvements: GRC103y exhibits double the yield strength at 800°C and 1.5x the yield strength at 1,400°C compared to baseline C103. The alloy also shows superior thermal stability: after one hour at 1,500°C, GRC103y retains 90% of its room temperature strength compared to only 67% for C103. Preliminary creep testing at 1,300°C and a stress of 50 MPa indicates significant improvements in creep resistance by 2539 times over baseline C103. Furthermore, GRC103y maintains excellent formability, allowing manufacturers to use traditional fabrication methods when desired. While NASA originally developed GRC103y for rocket propulsion and hypersonic vehicle applications, the alloy offers value across multiple industries. Aerospace companies can achieve weight savings or push systems to higher temperatures, while the alloy's compatibility with commercial oxidation coatings makes it suitable for environments requiring oxidation protection. GRC103y is currently available for patent licensing.

Shape memory alloys (SMAs) are metals that can return to their original shape following thermal input. They are commonly used as functional materials in sensors, actuators, clamping fixtures and release mechanisms across industries. SMAs can suffer from dimensional/thermal instability, creep, and/or low hardness, resulting in alloys with little to no work output in the long term. To combat these deficiencies, NASA has developed a process of incorporating nanoparticles of refractory materials (i.e., carbide, oxide, and nitride materials with high temperature resistance) into the alloys. Using various processing methods, the nanoparticles can be effectively mixed and dispersed into the metal alloys as shown in the figure below. In these processes the SMA and refractory material powder is mixed and the refractory nanoparticles incorporated through extrusions, melting, or directly used in additive manufacturing to create parts for applications across the aerospace, automotive, marine, or biomedical sectors. The nanoparticle dispersion is a controllable method to strengthen the SMAs, increasing the hardness of the alloys, reducing the impact of creep, and improving the overall dimensional and thermal stability of the alloys. The related patent is now available to license. Please note that NASA does not manufacture products itself for commercial sale.

Dispersion Enhanced Aluminum Alloys improve the additive manufacturing performance of high-strength aluminum alloys by modifying the alloy powder with uniformly dispersed nano-sized ceramic particles. Building on the dispersion and acoustic mixing methods developed during the creation of NASA Glenn's GRX-810 technology, researchers use an acoustic field to attach nanoscale alumina dispersoids to the surface of each aluminum alloy powder particle. During mixing, acoustic energy creates rapid micro-vibrations that cause the alumina particles to collide with the metal powder, embed against its surface, and distribute into a uniform shell that surrounds each particle. This produces a composite powder in which every aluminum particle carries its own evenly spaced ceramic nucleation sites. When the composite powder is delivered into an additive manufacturing process such as laser powder bed fusion or directed energy deposition, the aluminum alloy melts while the alumina dispersoids remain solid due to their significantly higher melting temperature. As the molten pool flows and mixes, the dispersoids remain suspended throughout the liquid region. During solidification, these solid particles interrupt grain growth and serve as nucleation points that promote the formation of fine equiaxed grains. This refined microstructure distributes thermal stresses more uniformly and disrupts the crack initiation mechanisms that typically occur in high-strength alloys like AA 2050. By stabilizing the alloy during solidification, the technology enables these advanced materials to be printed with greater reliability, improved geometric control, and more consistent mechanical behavior across the final product. The enhanced alloy technology is available for patent licensing.

SMAs are important multifunctional materials for the development of adaptive engineering structures. They exhibit a high work output that is competitive with, or superior to, conventional hydraulic, pneumatic, or electromagnetic actuators. While highly promising, SMAs are not always a practical alternative to conventional actuators because of their limited phase transformation temperatures and dimensional instability. Thanks to Glenn's innovative new SMA, that's about to change. Unlike traditional binary NiTi SMAs, Glenn's Ni-Ti-Hf-Zr SMA includes secondary, nanoscale precipitate phases that offer inherent dimensional stability to the material. Consequently, there is minimal to no need for training, resulting in much faster production times, lower processing costs, and a finished product with superior work outputs and better operational life. These Ni-rich alloys can be produced by Vacuum Induction Melting, Vacuum Arc Melting, Vacuum Arc Remelting, and Induction Skull Melting. Perhaps the most exciting characteristic of Glenn's SMA, however, is its ability to achieve a broad range of transformation temperatures suitable for high temperature (100 to 300°C), ambient, and sub-ambient temperature applications nearing -100°C. Furthermore, these temperatures can be tailored and fine-tuned though heat treatment to fit the needed parameters for the application of interest. In contrast, traditional NiTi SMAs exhibit fixed phase transformation at temperatures from slightly below room temperature to around 100°C. Glenn's Ni-Ti-Hf-Zr SMA opens the door to countless applications that can benefit from the unique properties of SMAs but require high durability and extreme temperature capability.

NASA's new Ni-based superalloy uses a powder metallurgy (PM) composition that inhibits the deleterious gamma-prime to gamma-phase transformation along stacking faults during high temperature creep deformation. Ni-base superalloys have excellent high temperature properties, mostly due to the presence of coherent precipitates. At higher temperatures, these precipitates are defeated by the diffusional shear dislocations producing intrinsic and extrinsic faults. Recent studies have found that, during deformation of turbine disk alloys at high temperature, Co, Cr, and Mo segregate to these faults (removing Ni and Al) inside the strengthening precipitates of these alloys. This represents a local phase transformation from the strengthening precipitate to the weaker matrix phase. Therefore, this elemental segregation significantly weakens the ability of a precipitate to withstand further deformation, producing faster strain rates in the alloy at higher temperatures. This invention presents a solution to prevent this type of segregation along these two faults to improve the creep properties of turbine disks and similar Ni-based alloys. By alloying a specific amount of eta phase formers (Ti, Ta, Nb, and Hf), the phase transformation to can be eliminated along 2-layer extrinsic stacking faults (SESFs) in precipitates without precipitating bulk eta phase. Also, by adding a certain amount of D019 formers (Mo and W), the phase transformation to can be mitigated along 1-layer intrinsic stacking faults (SISFs) without producing bulk sigma phase. This alloy composition incorporates both strengthening methods for use in jet turbine disks, though the composition has applications in other high-stress and/or high-temperature environments as are found in power plants, space launch systems, and other critical structural applications.