High-Temperature Single Crystal Preloader

NASA's new Ni-based superalloy uses a powder metallurgy (PM) composition that inhibits the deleterious gamma-prime to gamma-phase transformation along stacking faults during high temperature creep deformation. Ni-base superalloys have excellent high temperature properties, mostly due to the presence of coherent precipitates. At higher temperatures, these precipitates are defeated by the diffusional shear dislocations producing intrinsic and extrinsic faults. Recent studies have found that, during deformation of turbine disk alloys at high temperature, Co, Cr, and Mo segregate to these faults (removing Ni and Al) inside the strengthening precipitates of these alloys. This represents a local phase transformation from the strengthening precipitate to the weaker matrix phase. Therefore, this elemental segregation significantly weakens the ability of a precipitate to withstand further deformation, producing faster strain rates in the alloy at higher temperatures. This invention presents a solution to prevent this type of segregation along these two faults to improve the creep properties of turbine disks and similar Ni-based alloys. By alloying a specific amount of eta phase formers (Ti, Ta, Nb, and Hf), the phase transformation to can be eliminated along 2-layer extrinsic stacking faults (SESFs) in precipitates without precipitating bulk eta phase. Also, by adding a certain amount of D019 formers (Mo and W), the phase transformation to can be mitigated along 1-layer intrinsic stacking faults (SISFs) without producing bulk sigma phase. This alloy composition incorporates both strengthening methods for use in jet turbine disks, though the composition has applications in other high-stress and/or high-temperature environments as are found in power plants, space launch systems, and other critical structural applications.

Prior approaches to bonding a SiC sensor and a SiC cover member relied on either electrostatic bonding or direct bonding using glass frits. The problem with the former is that its relatively weak bond strength may lead to debonding during thermal cycling, while the latter requires the creation of apertures that can allow sealant to leak. Glenn's innovation uses NASA's microelectromechanical system direct chip attach (MEMS-DCA) technology that can be bulk-manufactured to reduce sensor costs. The MEMS-DCA process allows a direct connection to be made between chip and pins, thereby eliminating wire bonding. Sensors and electronics are attached in a single-stage process to a multifunctional package, which, unlike previous systems, can be directly inserted into the housing. Additional thick pins within the electrical outlet allow the package to be connected to external circuitry. Furthermore, because the top and bottom substrates' thermomechanical properties are similar to that of the sensors, the problem of mismatch in the coefficient of thermal expansion is significantly reduced, minimizing thermal cycling and component fatigue. By protecting sensors and electronics in temperatures up to 600°C, approximately twice what has previously been achievable, Glenn's innovation enables SiC components to realize one of their most exciting possibilities - direct placement within high-temperature environments.

Approximately 50 inches in diameter, Glenn's unique sealing system consists of multiple elements installed in a recessed rectangular sealing groove. The main sealing function is provided by an elastomer element (e.g., silicone) comprising one or more sealing wall(s) connected by a web. The wall(s) extend above the top of the sealing groove so they are compressed by the opposing mating surface during the sealing process. The retractable shroud element is installed between the wall(s), with its base resting atop the web of the sealing element. The shroud is typically composed of an elastomer material to allow for flexibility (which is essential to retraction), but it can also be made from thin metal or plastic materials. When the seal is no longer in use, a pair of V-shaped shroud "arms" extend upward from the base of the seal to cover the wall(s). A thin metal retainer is installed on top of the shroud, and fasteners pass through holes in the retainer, shroud, and sealing elements to secure the system to the base of the sealing groove. Metal washers are installed in these holes to provide a load path between the metal retainer and the surface of the sealing groove. The system can seal against either a flat metal surface or another seal of the same design. This sealing system has been designed to accommodate multiple sealing cycles and has exhibited extremely low leak rates, making it an attractive solution within a variety of industries from aerospace to agriculture.

NASA designed an inflatable habitat intended for space whose exterior incorporates an expandable layer known as the bladder – the main pressure shell of a module to which astronauts may reside while off-world. The bladder is made from a polymer material and is surrounded by protective layers to ensure it is not damaged and does not leak. On every module, there are two areas where the bladder and other flexible layers interface with the ends of a cylindrical core, at the bulkheads. Seals between the non-metallic bladder and the metallic bulkhead are critical in maintaining a safe pressurized environment for astronauts to live and work. With both bulkhead plates assembled, RTV silicone is deposited in specially designed channels which are sandwiched between the plates. After the channels are filled, a cure-in-place seal is formed between the bladder and the bulkhead. The RTV sealing method worked successfully during prototype testing as confirmed by a helium leak test and post-test visual inspection of the seals. In prototype testing, this method created a consistent and reliable seal between the bladder and bulkhead assembly replicated from the inflatable module design. The RTV sealing method may benefit terrestrial applications that may demand cure-in-place internal seals. The method could also innovate manufacturing processes for components by enhancing the speed of assembly while increasing seal integrity.

One inner insulative layer, and one outer robust ablative layer comprise the AMTPS technology. When applying the heat shield to the surface of a spacecraft, the insulative layer is printed first and primarily functions to reduce the amount of heat soak into the vehicle. The formulation of the insulative layer has a slightly lower density (as compared to the robust layer) and is adjusted using a differing constituent ratio of phenolic and/or glass microballoon material. Both formulations combine a phenolic resin with various fillers to control pre- and post-cure properties that can be adjusted by varying the carbon and/or glass fiber content along with rheology modifiers to enhance the fluid flow for deposition systems. The robust layer is applied next and functions as the ablative layer that ablates away or vaporizes when subjected to extremely high temperatures such as those achieved during atmospheric entry. The formulation of the robust layer produces a gas layer as it vaporizes in the extreme heat that acts as a boundary layer. This boundary prevents heat from further penetrating the remaining robust material by pushing away the even hotter shock layer. The shock layer is a region of super-heated compressed gas, positioned in front of the Earth-facing bottom of the spacecraft during atmospheric entry, that results from the supersonic shockwave generated. Commercial space applications for this AMTPS technology include use on any spacecraft that transits a planetary or lunar atmosphere such as Mars or Saturn’s moon Titan. Additionally, the invention may be useful for launch system rockets to provide heat shielding from atmospheric reentry or to protect ground equipment on the launch pad from rocket exhaust plumes. As the number of government and commercial space missions to primary Earth orbits, the Moon, and the Solar System increase, there will be a growing need for cost-effective, on-demand, and timely fabrication of heat shields for space-related activities. AMTPS Formulations – Insulative and Robust Variation is at a technology readiness level (TRL) 5 (component and/or breadboard validation in laboratory environment) and is now available for patent licensing. Please note that NASA does not manufacture products itself for commercial sale.