Pouch Cell Format Li-ion Calorimeter

Among the enhancements reflected in the Next Generation Li-ion Calorimeter is a rigidly wired system that allows direct mounting of thermocouples into key component locations to better capture thermal signature data during testing and improve thermocouple reliability. The ejecta mating chambers have also been modified for better thermal containment and easier system disassembly. Additionally, the system facilitates an easier access, user-friendly Destructive Physical Analysis (DPA) process between uses, and reflects durability improvements in the face of repetitive heat cycling. A clean-sheet redesign was undertaken to create a configurable insula-tion case with an interchangeable “window” section, tailored to the ex-perimental environment. For NASA’s Energy Systems Test Area (ESTA) evaluation, a window with the original foam is installed to maintain ther-mal insulation performance. In contrast, for synchrotron experiments, this section is replaced with an aluminum window that eliminates foam-related X-ray scattering. This modification has substantially improved X-ray radiography resolution, enabling clearer imaging of fine internal battery features during thermal runaway events. Moreover, the insulation case was designed to provide system fire-proofing for both the chamber and pouch cell testing case configurations. Lastly, a control switchbox is also being developed to work with the latest generation calorimeter. It allows users to remotely operate the TR trigger mechanism from a control room, automatically terminate power in a prescribed amount of time to prevent a fire caused by overheating, and provides lit indicators to inform the user of ready or fault states.

Li-ion batteries are an integral part of energy storage systems used in NASA's Exploration program, as well as many modern terrestrial industries. Innovators at the NASA Johnson Space Center wanted a better way to measure total and fractional heat response of specific types of Li-ion cells when driven into a thermal runaway condition. They developed a calorimeter with at least two chambers, one for the battery cell under test and at least one other chamber for receiving the thermal runaway ejecta debris. Both are designed to be structurally strong and thermally insulated. When the test cell is intentionally driven into thermal runaway, ejecta explodes into the ejecta chamber and is decelerated and collected. Thermal sensors are strategically placed throughout the chambers to collect thermal data during the test. Customized software analyzes the thermal data and determines key calorimeter parameters with a high degree of accuracy.

The Ram-Dent Thermal Runaway Triggering Device is capable of trig-gering mild short circuits that are similar to internal defects, and more extreme short circuits that are comparable to those initiated by an implanted internal short circuit device – all without having to modify the battery cell in any way. The device imparts a high velocity, low mass blunt impact onto a small surface area of a Li-ion battery cell can wall allowing a small hemispherical dent to form. This impact deforms and tears the internal separator of the battery cell, causing a short circuit, and induces thermal runaway. Several methods for initiating TR on demand currently exist, but they have characteristics and biases that make them more unfavorable for certain testing objectives. Heat-based insult in any form requires additional thermal energy to be applied to the battery cell, potentially distorting the signal-to-noise ratio in FTRC measurement, and increas-ing the severity of failure beyond what is intended. This methodology also requires time to heat the battery cell to critical temperature, and it potentially weakens the battery cell can wall causing abnormal kinetics and rupture. Mechanical insult methodologies, such as crush testing and nail penetration, have unique applications but rely on deformation of the battery cell itself which alters the flow characteristics of internal gases and the material integrity of the battery cell. This technology aims to solve these limitations by implementing a cost-effective method to create a natural short circuit failure in Li-ion batteries that does not alter nominal vent paths and energy yields, potentially yielding the most unbiased calorimeter tallies yet. The Ram-Dent Thermal Runaway Triggering Device is at a technology readiness level (TRL) 4 (component and/or breadboard validation in laboratory environment) and is now available for patent licensing. Please note that NASA does not manufacture products itself for commercial sale.

This technology is based upon a 120-watt IR laser is coupled to a fiber optic cable that is routed from the output of the laser into a series of focusing optics which directs energy onto a battery cell mounted to a test stand. When activated, heat from the laser penetrates the metal housing, heating the internals of the cell. At a specific temperature, the separator in the first few layers of the cell melts allowing the anode and cathode to make contact and initiates an internal short circuit. The internal short circuit then propagates throughout the battery eventually causing thermal runaway. The lower the wavelength of the laser used to produce the thermal runaway, the more heat-energy will be absorbed into the cell producing a faster result. The fiber optic cable can be terminated into a series of optics to focus the laser at a specific target, or the fiber optic cable can be stripped bare and placed next to the target to heat an isolated location. This method can also be used on a wide variety of cells, including Li-ion pouch cells, Li-ion cylindrical cells and Li-ion Large format cells. The innovation Triggering Li-ion Cells with Laser Radiation is at TRL 6 (which means a system/subsystem prototype has been demonstrated in a relevant environment) and the related patent application is now available to license and develop into a commercial product. Please note that NASA does not manufacture products itself for commercial sale.

The CFRP sleeve was originally intended for crewed space flight lithium-ion 18650 battery packs rated over 80 Watt-hours (Wh), which are required to be passively propagation-resistant for increased safety. Previous battery designs have addressed SWR propagation by using aluminum or steel interstitial materials to prevent SWRs from directly impacting neighboring cells, but these materials were underperforming. During testing of 18650 battery cells, it was discovered that cells over 2.6Ah in capacity can have an undesirable failure mode in which the cell wall will rupture or breach during a thermal runaway (TR) event sending heat and ejecta into an undesirable direction. TR is typically triggered when heat produced by the battery cell’s exothermic reaction leads to increased and escalating internal cell temperature, pressure, and boiling of the electrolytes. When internal cell pressure exceeds the cell’s safety relief mechanism, rupture or bursting can occur, initiating a cell-to-cell propagation that in turn results in a battery pack fire. By adding a carbon fiber reinforced polymer (CFRP) sleeve to cylindrical battery cells, a sidewall rupture (SWR) can be prevented from occurring or propagating. In initial testing, there were no SWRs of a battery cell using a CFRP sleeve. This result is believed to be due in part to a unique characteristic of CFRP sleeves compared to other materials. Carbon fiber material has a negative coefficient of expansion and accordingly shrinks when heated, while steel and aluminum expand. The shrinking of the CFRP sleeve when heated compresses the cell located within it, significantly aiding in the prevention of SWR. This technology can be implemented into other multi-physics battery safety models to guide the design of the next generation of battery cells and battery packs. This thermal runaway propagation resistant technology has a technology readiness level (TRL) of 6 (System/sub-system model or prototype demonstration in an operational environment) and is now available for patent licensing. Please note that NASA does not manufacture products itself for commercial sale.