NanoWire Glass Switch for Radio Frequency

The nanoionic-based switches developed by NASA's Glenn Research Center exploit the properties of some amorphous materials that can incorporate relatively large amounts of metal and behave as solid electrolytes. As with liquid electrolytes found in lead-acid batteries, for example, solid electrolytes consist of mobile ions which undergo oxidation/reduction reactions at the anode and cathode of the system. The ionic conductivity of such a material can be of the same order of magnitude as the electronic conductivity of a semiconductor but without the drawbacks of an electromechanical device. In the nanoionic switch, ions are formed at an anode and migrate into the solid electrolyte, while electrons are injected from a cathode, thereby causing the growth of metal nanowires through the electrolyte from the cathode to the corresponding anode when a positive DC bias is applied. Once a nanowire has grown sufficiently to form an electrically conductive path between the electrodes, the switch is closed and no electric power is needed to maintain the connection, unlike in a MEMS or semiconductor-based switch. Moreover, the process of making the connection can easily be reversed by applying a negative bias, causing the wires to ungrow and the switch to open. Thus, NASA's state-of-the-art device is a reversible electrochemical switch that can have geometric features as small as nanometers. The process time for making or breaking the connection is very brief -- about a nanosecond. In addition, this nanoionic material can be deposited in such a way to form multilayer control circuits, which has the potential to minimize circuit footprints, reduce overall circuit losses, and provide unprecedented ease of integration.