Atomic Layer Deposition Chamber for Automated Semiconductor Processing Equipment

Manufacturing
Atomic Layer Deposition Chamber for Automated Semiconductor Processing Equipment (NPO-TOPS-49)
Reduces sample contamination, lowers costs, and integrates with host systems
Overview
Researchers at NASA's Jet Propulsion Laboratory (JPL) have designed a novel atomic layer deposition (ALD) chamber that enables integration with a molecular beam epitaxy (MBE) system in an unbroken vacuum system. This novel innovation supports automated sample transfer and highly automated semiconductor processing equipment. JPL's ALD chamber design offers a variable volume and can be configured to process wafers in a facedown orientation. These key features reduce chip processing costs and allow wafers to be processed in the same orientation as in MBE and other host systems. Encapsulating the ALD and MBE systems in a single vacuum system eliminates exposure to the atmosphere and significantly reduces contamination risks.

The Technology
Researchers at JPL have redesigned a typical standalone ALD chamber in a way that is fully compatible with automated semiconductor processing systems, yet maintains the benefits of a conventional ALD chamber—a small-volume reaction chamber, heated sample holders, and laminar gas flow. The unique three-part ALD chamber incorporates the heater, sample transfer mechanism, and laminar gas injectors into a collapsing pancake design, which enables self-assembly within the reaction chamber. The design utilizes a facedown sample arrangement, which reduces particulate contamination compared to standard faceup ALD systems. Integration with the MBE system also ensures that the ALD chamber remains clean and contaminant-free compared with conventional shared-use, standalone ALD systems. Further, the chamber is engineered to use the fewest number of actuators and provide the greatest design flexibility for all types of host systems and ALD processes. Because no automated system currently exists that incorporates both MBE and ALD processes in one unbroken vacuum system, atmosphere exposure is unavoidable when transferring components for processing. Encapsulating ALD and MBE processing chambers offers a significant process improvement and reduces the cost of producing components with precise MBE films. This innovation is anticipated to add great value to advanced image detector processing at JPL, as well as to the semiconductor industry. Originally developed for specific use with a JPL-developed MBE system, this innovation would be useful for any semiconductor industry customer seeking to prevent atmosphere exposure to MBE films prior to ALD processing in an automated system.
Transparent perspective view illustrating an ALD chamber when not processing wafers.
Benefits
  • Lower cost: Microencapsulation allows smaller amounts of precursor materials to be used
  • Automated transfer: Components are oriented in the same direction to allow for automated sample transfer between processing chambers
  • Flexible: Integrates easily with existing host systems
  • Enhanced cleanliness: Reduces sample contamination risk due to facedown orientation and intra-vacuum integration with host systems

Applications
  • Semiconductor processing
  • Nanotechnology
  • Spin transport electronics
  • Advanced image detectors
Technology Details

Manufacturing
NPO-TOPS-49
NPO-49739-1
Patent Pending
Patent Pending
Similar Results
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Tannin Based Foams Utilizing 10B-Al-N Atomic Layer Deposition
Commercially available Borric Acid can be deposited along with alumina via a three step ALD process where a boron-10-alumina complex is deposited. The Boron in the alumina complex allows for better gamma ray capture at a significant weight reduction. Boron has one of the largest neutron absorption cross sections of all the elements of the periodic table, and nitrogen has a larger neutron absorption cross section than carbon. Borates play a key role in the operation of nuclear power plants, and they are essential in the safety and control of pressurized water reactors (PWRs) and boiling water reactors. Boron 10 Metal (Boron-10) is a stable (non-radioactive) isotope of Boron. It is both naturally occurring and a produced by fission, can be found via Borric10 acid. By mixing the acid with methanol a precursor has been developed to inject into an ALD reactor system. The super cycle of borric-10 acid along with alumina precursors and water creates the B10-Al-O or N composite. Tannins are nontoxic, renewable, cheap and abundant polyphenolic oligomers extracted from tree barks. They are versatile, natural, phenolic compounds that may be extracted from many tree species. Condensed, flavonoid tannins are considered as an ‘eco-friendly’ base of resin when compared to homologous phenolic materials of petrochemical origin. The polyphenolic structure of condensed tannins explains their reactivity as a base of resin and their high-carbon yield. Tannin extraction from tree bark is an easy and ecological process, using only hot water and a few additives.
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Epitaxy of SiGe and Other Compound Semiconductors
Several of the patented methods included in this suite of technologies enable super-hetero-epitaxy of rhombohedral/cubic compound semiconductors on specially oriented trigonal (e.g. sapphire) or hexagonal (e.g. quartz) crystal wafer substrates. This includes alignment of the growth crystal lattice with the underlying substrate lattice to minimize misfit strain-induced dislocation defects in the growing crystal. Thus thicker, defect-free crystal layers can be made. Rhombohedral/Cubic crystal twin defects which is 60 degree rotated on [111] orientation in a rhombohedral/cubic SiGe layer structure can be reduced to well less than 1% by volume, essentially providing a defect-free semiconductor material. Alternately, engineered lattice structures with a high degree of twinning can provide SiGe with improved thermoelectric properties due to the phonon scattering that inhibits thermal conduction without compromising electrical conductivity. Additional patented technologies in this suite provide for physical vapor deposition (PVD) growth methods utilizing molten sputtering targets and thermal control of heated substrates, including electron beam heating, in order to give the atoms in the sputtered vapor or on the substrate surface the energy needed for the desired crystal growth. The remaining patented technologies enable x-ray diffraction methods for detecting and mapping crystal twin defects across the entire as-grown semiconductor layer. These defects are critical to the performance of any semiconductor device manufactured from such compound semiconductor materials.
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Reduced PIC fabrication cost by one-step method
The new fabrication method is an electron lithography scheme enabling monolithic integration of multiple photonic devices on a single PIC. The technology was demonstrated by integrating both a widely-tunable distributed Bragg reflector (DBR) and distributed feedback (DFB) lasers on the same substrate. By controlling the central gap width and etch depth along the laser mirror length (shown in the figure below) the reflectivities can be tuned and the desired laser characteristics can be achieved without additional lithography cycles. Initially demonstrated on an indium phosphide substrate with DBR and DFB elements, the platform technology shows promise for various other materials and devices like III-V and II-VI semiconductors, silicon-on-insulator (SOI), and planar lightwave circuits (PLCs). With this versatility, the invention described here can streamline PIC production across diverse applications. Proof-of-concept results showcase the lithographic technique’s ability to produce high-performance photonic devices with side-mode suppression ratios over 50 dB (figure on the right) and output powers exceeding 5 mW. These metrics, combined with the lithographic simplicity, highlight the technology’s potential to reduce costs and accelerate PIC manufacturing. Please note that NASA does not manufacture products itself for commercial scale.
Front
Low-Cost Detection of Thin Film Stress during Fabrication
Traditional methods of determining film stress use ex-situ deflectometry techniques and require significant and costly modifications to the vacuum chamber to allow optical access to the substrate. These techniques determine film stress by measuring the change in substrate curvature resulting from stress. NASA's method infers the stress-induced substrate curvature by measuring the out-of-plane displacement of a single point on the substrate using a fiber optic displacement sensor (Figure 1). The probe gains optical access to the substrate through a normal fiber optic feed-through common in vacuum systems. In turn, this simplification leads to a significant reduction in cost, complexity, and system requirements. It also eliminates interference effects. With a measurement sensitivity of 0.05 N/m, the method is comparable in sensitivity with MOSS and could potentially rival the sensitivity of the microcantilever technique. NASA's method can be used to measure the stress during film growth for heated substrates, as well as the evolution of stress during thermal annealing processes. The technique can be used in a variety of thin film applications, with no limitation on substrate size or reflective characteristics of deposited films. The methodology has been proven with magnetron sputtering of chromium films, where it was used to adjust process gas pressure to achieve zero stress.
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High Mobility Transport Layer Structures for Rhombohedral Si/Ge/SiGe Devices
Performance of solar cells and other electronic devices such as transistors can be improved greatly if carrier mobility is increased. Si and Ge have Type-II bandgap alignment in cubically strained and relaxed layers. Quantum well and super lattice with Si, Ge, and SiGe have been good noble structures to build high electron mobility layer and high hole mobility layers. However, the atomic lattice constant of Ge is bigger than that of Si and direct epitaxial growth generates large density of misfit dislocations which decrease carrier mobility and shorten device life time. So it required special buffer layers such as super lattice or gradient indexed layers to grow Ge on Si wafers or Si on Ge wafers. The growth of these buffer layers takes extra effort and time such as post-annealing process to remove dislocations by dislocation gliding inside buffer layer. This invention is a fabrication method for high mobility layer structures of rhombohedrally aligned SiGe on a trigonal substrate. The invention utilizes C-plane (0001) Sapphire which has a triangle plane, and a Si (Ge) (C) (111) crystal or an alloy of group TV semiconductor (111) crystal grown on the Sapphire.
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