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For years, NASA and the battery industry have been improving passive propagation resistant (PPR) Li-ion battery cell technology by enhancing their material and design choices. These efforts help ensure that a single cell’s TR event does not overheat adjacent cells or the entire battery pack ultimately causing fire or explosion. To improve cell integrity, single cells within battery packs are triggered into TR so that the battery pack can be analyzed for its TR resistance. ThermoArc operates by initiating a plasma arc, capable of delivering thermal energy up to 100W, to a very small (1mm diameter) section of the cell. The extremely localized high heat flux rapidly degrades a small section of the internal cell separator, resulting in a short circuit that leads to TR. This technology comprises several components: a high-turn-ratio step-up transformer capable of producing a minimum of 1,000 V upon the secondary winding, an H-bridge electronic circuit to drive the transformer on the primary side, two tungsten electrodes to deliver the plasma arc, and a power supply unit. ThermoArc applications may exist in any Li-ion battery cell/pack testing application where TR must be induced in an individual cell. Such applications could include testing of PPR battery packs to ensure single cell runaway does not cause catastrophic damage, more general battery destructive testing designed to better understand battery failure states, or other experimental testing. Companies interested in licensing this innovation may include those that manufacture internal short-circuit (ISC) cells or other devices used to induce TR at the individual cell level, battery testing firms, and Li-ion battery manufacturers with a focus on Li-ion battery packs for critical applications. ThermoArc is at a technology readiness level (TRL) 5 (component and/or breadboard validation in laboratory environment) and is now available for patent licensing. Please note that NASA does not manufacture products itself for commercial sale.

This technology is based upon a 120-watt IR laser is coupled to a fiber optic cable that is routed from the output of the laser into a series of focusing optics which directs energy onto a battery cell mounted to a test stand. When activated, heat from the laser penetrates the metal housing, heating the internals of the cell. At a specific temperature, the separator in the first few layers of the cell melts allowing the anode and cathode to make contact and initiates an internal short circuit. The internal short circuit then propagates throughout the battery eventually causing thermal runaway. The lower the wavelength of the laser used to produce the thermal runaway, the more heat-energy will be absorbed into the cell producing a faster result. The fiber optic cable can be terminated into a series of optics to focus the laser at a specific target, or the fiber optic cable can be stripped bare and placed next to the target to heat an isolated location. This method can also be used on a wide variety of cells, including Li-ion pouch cells, Li-ion cylindrical cells and Li-ion Large format cells. The innovation Triggering Li-ion Cells with Laser Radiation is at TRL 6 (which means a system/subsystem prototype has been demonstrated in a relevant environment) and the related patent application is now available to license and develop into a commercial product. Please note that NASA does not manufacture products itself for commercial sale.

Typical concentration sensors, like the one initially used in the UWMS, rely on changes in electrical conductivity to measure the concentration of a solution. These measurements using conductivity are prone to voltage drift over time, leading to unreliable measurements as the sensor ages. The optical sensor developed here uses light scattering to measure the solution concentration without the issue of voltage drift. In this sensor, light from a green LED is passed into the sensor housing where it hits a first detector (i.e., a photodiode) to establish a reference of the amount of light before scattering. Simultaneously, the light from the LED scatters through the pretreat solution and then hits a second photodiode to measure the amount of light after scattering. The difference between the amount of light measured by the two detectors is used to calculate the concentration of the pretreat solution (based upon Beer’s Law). The optical concentration sensor has been demonstrated to effectively measure pretreat concentrations in both still and flowing liquid conditions and is resistant to contamination issues as necessitated by the UWMS. The optical pretreat concentration sensor is at technology readiness level (TRL) 4 (component and/or breadboard validation in laboratory environment) and is available for patent licensing.

One of the central objectives of this project was the development and characterization of a 3D mineralized tissue model system in which the effects of mechanical load (e.g., compression loading, tension, vibration, etc.) on the cellular responses of osteoblasts and osteoclasts could be investigated. After introducing mineralization agents to the culture, the constructs take on a bone-like appearance and have a more rigid structure suitable for being tested. Testing of the mineralized constructs confirmed the presence of calcium through a crystalline matrix histochemical stain. The central core is void of necrotic material, instead filled by a crystalline matrix with embedded nucleated cells. Remarkably, the nucleated cells do not express osteoblast markers, indicating differentiation to the in vivo cell type known as the osteocyte. In addition, as is characteristic to native periosteum, osteoclast precursor cells were imaged and proven to naturally arrange as an outer layer of the mineralized bone tissue construct. Development of this model will provide a unique venue for testing proposed countermeasures to space flight-induced bone loss. It will also allow a mechanistic approach in the modulation of cell signaling at the cellular level within the bone matrix. The Development And Characterization Of A Three-Dimensional Tissue Culture Model Of Bone is a technology readiness level (TRL) 6 (system/subsystem prototype demonstrated in a relevant environment). The innovation is now available for your company to license. Please note that NASA does not manufacture products itself for commercial sale.

In vitro three-dimensional (3D) human broncho-epithelial (HBE) tissue-like assemblies (3D HBE TLAs or TLAs) were engineered in modeled microgravity using rotating wall vessel technology (pictured above) to mimic the characteristics of in vivo tissue. The TLAs were bioengineered onto collagen-coated cyclodextran beads using primary human mesenchymal bronchial-tracheal cells (HBTC) as the foundation matrix and an adult human broncho-epithelial immortalized cell line (BEAS-2B) as the overlying component. The resulting TLAs share significant characteristics with in vivo human respiratory epithelium including polarization, tight junctions, desmosomes, and microvilli. The presence of tissue-like differentiation markers including villi, keratins, and specific lung epithelium markers, as well as the production of tissue mucin, further confirm these TLAs have differentiated into tissues functionally like in vivo tissues. TLAs mimic aspects of the human respiratory epithelium and provide a unique capability to study the interactions of respiratory viruses and their primary target tissue independent of the host's immune system. The innovation "Methods For Growing Tissue-Like 3D Assemblies Of Human Broncho-Epithelial Cells" is at Technology Readiness Level (TRL) 6 (which means system/subsystem prototype demonstration in a relevant environment) and the related patent is now available to license for development into a commercial product. Please note that NASA does not manufacture products itself for commercial sale.

The Multi-Layer NTAC is comprised of a gamma-ray source and various layers of emitters, collectors, and insulators. Ideal emitter materials include elements with high atomic numbers, while ideal collector and insulator materials include elements with low atomic numbers. A high-energy gamma-ray (tens of keV to MeV) is used to liberate a large number of intra-band, inner-shell electrons from atoms within the emitter material for power generation through the primary interactions of photoelectric, Compton scattering, photonuclear, and electron/positron pair production processes. Secondary and tertiary electrons are liberated in the avalanche process as well. If a power conversion process effectively utilizes all liberated electrons in an avalanche mode through a power conversion circuit, the power output is drastically increased. Because power conversion is determined by the absorption rate of high energy photons, increasing power output requires either thicker collector material or a sufficient number of layer structures to capture the high energy photons, leaving no liberated electrons escaping (i.e., minimizing the leak of radioactive rays). The selection of materials, the thicknesses of the emitter, collector, and insulator, as well as the number of NTAC layers required are all determined by the energy of photon source. The thermal energy from radioactive decay can also be converted to electricity using a thermoelectric device to further increase power output. The Multi-Layer NTAC technology can be manufactured using existing semiconductor fabrication technology and can be tailored for small-to-large scale power needs, including kilowatt and megawatt applications.

Storage and transfer of fluid commodities such as oxygen, hydrogen, natural gas, nitrogen, argon, etc. is an absolute necessity in virtually every industry on Earth. These fluids are typically contained in one of two ways; as low pressure, cryogenic liquids, or as a high pressure gases. Energy storage is not useful unless the energy can be practically obtained ("un-stored") as needed. Here the goal is to store as many fluid molecules as possible in the smallest, lightest weight volume possible; and to supply ("un-store") those molecules on demand as needed in the end-use application. The CFC concept addresses this dual storage/usage problem with an elegant charging/discharging design approach. The CFC's packaging is ingeniously designed, tightly packing aerogel composite materials within a container allows for a greater amount of storage media to be packed densely and strategically. An integrated conductive membrane also acts as a highly effective heat exchanger that easily distributes heat through the entire container to discharge the CFC quickly, it can also be interfaced to a cooling source for convenient system charging; this feature also allows the fluid to easily saturate the container for fast charging. Additionally, the unit can be charged either with cryogenic liquid or from an ambient temperature gas supply, depending on the desired manner of refrigeration. Finally, the heater integration system offers two promising methods, both of which have been fabricated and tested, to evenly distribute heat throughout the entire core, both axially and radially. NASA engineers also applied the CFC to a Cryogenic Oxygen Storage Module to store oxygen in solid-state form and deliver it as a gas to an end-use environmental control and/or life support system. The Module can scrub out nuisance or containment gases such as carbon dioxide and/or water vapor in conjunction with supplying oxygen, forming a synergistic system when used in a closed-loop application. The combination of these capabilities to work simultaneously may allow for reduced system volume, mass, complexity, and cost of a breathing device.

The technology utilizes photopolymer droplets (invisible to the digital radiograph) with embedded radiopaque fragments to create randomized fingerprints on battery samples. The droplets are deposited using a jig (see figure on right) that precisely positions samples. Then, at different points during battery R&D testing or use, digital radiography imaging with micron-level resolution can be performed. The high-resolution imaging required to detect dendrite formation requires images to be collected in multiple “tiles” as shown below. The randomized fingerprints uniquely identify relative positioning of these tiles, allowing rapid assembly of composite high-resolution images from multiple tiles. This same composite creation process can be used for images taken at a series of points in time during testing, and background subtraction can be applied to efficiently compare how the battery is changing over successive charge/discharge cycles to identify dendrite formation. This inspection technique is proven effective for thin-film pouch cell prototypes at NASA, and it works well at the lowest available x-ray energy level (limiting impact on the samples). The Fingerprinting for Rapid Battery Inspection technology is available for patent licensing.

The R2 hand and forearm assembly represents the cutting edge of humanoid robotics technologies. The highly modular design provides significant improvements over prior humanoid robotic hands, especially in the areas of strength, speed, sensing, and ability to approximate human grasps. <i>Hand, Finger, and Wrist Assembly Design:</i> The robotic humanoid lower arm design (U.S. Patent No. 9,505,134) includes novel robotic finger (U.S. Patent No. 8,562,049), thumb (U.S. Patent No. 8,424,941), and wrist (U.S. Patent No. 8,498,741) assemblies. <i>Actuation & Control System:</i> A novel finger actuation system (U.S. Patent No. 8,467,903) – comprised of an actuator, tendon, conduit, tension sensor (U.S. Patent No. 8,371,177), and terminator – is perhaps the primary enabling technology for R2’s compact, high performance robotic hand. The actuation system is packaged in the wrist (U.S. Patent No. 8,401,700) and reduces the number of actuators, providing significant space savings. Control systems include methods for tensioning (U.S. Patent Nos. 8,412,376, 8,618,762, & 8,056,423) and controlling torque (U.S. Patent No. 8,565,918) of the tendon-driven robotic fingers. The finger actuation control system (U.S. Patent No. 8,489,239) can operate using force- or position-based control laws. <i>Tactile System:</i> R2’s hands feature an innovative tactile system that grant the robot a sense of touch (e.g., measurement of external contact forces, shear force, and slippage of objects held in the hand) – an important requirement for robots designed to perform complex tasks in an automated fashion. The tactile system is enabled by novel six degree of freedom (DoF) force torque sensors (U.S. Patent No. 7,784,363), three of which are integrated into the fingers (at the proximal, medial, and distal phalanges) and two in the thumb (medial and distal phalanges). A calibration system (U.S. Patent No. 8,265,792) ensures the sensors maintain high accuracy throughout operation. <i>Autonomous Grasping:</i> A novel grasp assist device (U.S. Patent No. 9,878,452 & 9,067,319) enables reliable, autonomous interaction with a broad range of objects (e.g., tools). A particle filter-based contact state estimation device (U.S. Patent No. 8,280,837) performs object localization and characterization.

NASA’s pneumatic nail penetration trigger system embodies a fast and consistent nail penetration and retraction tool that tests battery cells within various steel and mylar enclosures. It is operated remotely with electric power and shop air pressure inputs. The trigger system is controlled by a solenoid valve and drives a nail to a set distance at 100 m/s for a precise and repeatable penetration injury to a battery cell. Contributing to the trigger system’s precision and repeatability is the nail penetration adapter that aligns the battery cell test enclosure with the trigger system and guides the nail by its internal barrel. The tip of the adapter threads into a variety of NASA battery cell test enclosures and provides an internal seating stop to ensure a proper targeting depth. On the actuator side of the adapter, two quick-release pins connect the adapter to the actuator mount which is bolted to the actuator subassembly. Removal of these pins readily allow for separation of the nail penetration adapter from the actuator mount and subassembly. During a TR event, the adapter is also designed to prevent flames, sparks, and ejecta from traveling into the actuator subassembly. While the versatile nail penetration adapter was originally configured to interface with NASA’s Fractional Thermal Runaway Calorimeter (FTRC), a blast plate test platform (BPTP), or cell enclosure for passive propagation resistant (PPR) methods, the adapter could be modified for commercial use with other battery testing systems. Companies interested in this technology may include those seeking to improve the safety of Li-ion battery cells and packs along with vertically integrated companies performing in-house TR tests during development of electrified systems like electric vehicles (EVs), electric vertical takeoff and landing (eVTOLs) vehicles, and electronic spacecraft components.