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The CFRP sleeve was originally intended for crewed space flight lithium-ion 18650 battery packs rated over 80 Watt-hours (Wh), which are required to be passively propagation-resistant for increased safety. Previous battery designs have addressed SWR propagation by using aluminum or steel interstitial materials to prevent SWRs from directly impacting neighboring cells, but these materials were underperforming. During testing of 18650 battery cells, it was discovered that cells over 2.6Ah in capacity can have an undesirable failure mode in which the cell wall will rupture or breach during a thermal runaway (TR) event sending heat and ejecta into an undesirable direction. TR is typically triggered when heat produced by the battery cell’s exothermic reaction leads to increased and escalating internal cell temperature, pressure, and boiling of the electrolytes. When internal cell pressure exceeds the cell’s safety relief mechanism, rupture or bursting can occur, initiating a cell-to-cell propagation that in turn results in a battery pack fire. By adding a carbon fiber reinforced polymer (CFRP) sleeve to cylindrical battery cells, a sidewall rupture (SWR) can be prevented from occurring or propagating. In initial testing, there were no SWRs of a battery cell using a CFRP sleeve. This result is believed to be due in part to a unique characteristic of CFRP sleeves compared to other materials. Carbon fiber material has a negative coefficient of expansion and accordingly shrinks when heated, while steel and aluminum expand. The shrinking of the CFRP sleeve when heated compresses the cell located within it, significantly aiding in the prevention of SWR. This technology can be implemented into other multi-physics battery safety models to guide the design of the next generation of battery cells and battery packs. This thermal runaway propagation resistant technology has a technology readiness level (TRL) of 6 (System/sub-system model or prototype demonstration in an operational environment) and is now available for patent licensing. Please note that NASA does not manufacture products itself for commercial sale.

The SABERS innovators developed novel lithium-sulfur designs, including sulfur-selenium on graphene cathodes, and lightweight bipolar plate stacking and packaging designs. SABERS is unique in several aspects: it deploys graphene-based manufacturing processes for the cathode and bipolar plates, and it uses a solid-state electrolyte in place of the liquid electrolyte found in other lithium-sulfur battery designs. The team has achieved energy densities over 500 W-hr/kg, and further improvements are expected. SABERS can meet the high-power requirements needed for aircraft take-off. SABERS is lightweight, safe, robust, and reliable. Furthermore, its manufacturing processes are scalable and environmentally friendly. Coin cell and pouch prototypes have been demonstrated to date. Development efforts continue and new portfolio innovations are expected. Major component technologies in SABERS include the following (as listed here and shown in the figure below). <ul><li>S/Se Cathode Sulfur/Selenium on graphene scaffold (LAR-19556-1, LEW-20228-1) <li>Solid Electrolyte Solid-state electrolyte composites (LEW-20445-1) <li>Bipolar Stack Graphene plates (LAR-20257-1) <li>Li-Metal Anode (Proprietary, under development) <li>Packaging (Proprietary, under development)</ul> Robust computational models have been developed to support the battery materials design and are available to licensees to evaluate and optimize different materials combinations and performance targets.

This technology is based upon a 120-watt IR laser is coupled to a fiber optic cable that is routed from the output of the laser into a series of focusing optics which directs energy onto a battery cell mounted to a test stand. When activated, heat from the laser penetrates the metal housing, heating the internals of the cell. At a specific temperature, the separator in the first few layers of the cell melts allowing the anode and cathode to make contact and initiates an internal short circuit. The internal short circuit then propagates throughout the battery eventually causing thermal runaway. The lower the wavelength of the laser used to produce the thermal runaway, the more heat-energy will be absorbed into the cell producing a faster result. The fiber optic cable can be terminated into a series of optics to focus the laser at a specific target, or the fiber optic cable can be stripped bare and placed next to the target to heat an isolated location. This method can also be used on a wide variety of cells, including Li-ion pouch cells, Li-ion cylindrical cells and Li-ion Large format cells. The innovation Triggering Li-ion Cells with Laser Radiation is at TRL 6 (which means a system/subsystem prototype has been demonstrated in a relevant environment) and the related patent application is now available to license and develop into a commercial product. Please note that NASA does not manufacture products itself for commercial sale.

The Multi-Layer NTAC is comprised of a gamma-ray source and various layers of emitters, collectors, and insulators. Ideal emitter materials include elements with high atomic numbers, while ideal collector and insulator materials include elements with low atomic numbers. A high-energy gamma-ray (tens of keV to MeV) is used to liberate a large number of intra-band, inner-shell electrons from atoms within the emitter material for power generation through the primary interactions of photoelectric, Compton scattering, photonuclear, and electron/positron pair production processes. Secondary and tertiary electrons are liberated in the avalanche process as well. If a power conversion process effectively utilizes all liberated electrons in an avalanche mode through a power conversion circuit, the power output is drastically increased. Because power conversion is determined by the absorption rate of high energy photons, increasing power output requires either thicker collector material or a sufficient number of layer structures to capture the high energy photons, leaving no liberated electrons escaping (i.e., minimizing the leak of radioactive rays). The selection of materials, the thicknesses of the emitter, collector, and insulator, as well as the number of NTAC layers required are all determined by the energy of photon source. The thermal energy from radioactive decay can also be converted to electricity using a thermoelectric device to further increase power output. The Multi-Layer NTAC technology can be manufactured using existing semiconductor fabrication technology and can be tailored for small-to-large scale power needs, including kilowatt and megawatt applications.

This technology exploits the inherently passive nature of RFID to approximate the services provided by traditional active Internet of Things (IOT) protocols like ZigBee and Bluetooth. A novel store-and-forward overlay on COTS RFID protocols allows an RFID active tags to transit through an ecosystem of RFID interrogators, exploiting contact opportunities as they arise and quietly transfers sensor readings at nearly no power cost to the RFID active tag. Specific intelligence built into both the interrogator and the tag leverages the RFID tag user memory (UM) as a stand-in IOT interface. The tag operates by sampling data into timestamped packets and loads them into tag memory. When an interrogator in the ecosystem realizes that a tag is in view and that there is unrecovered data on the tag, it takes custody of the sensor data packet and offloads the data into a database. A smart scheduler reads from the population of interrogators and schedules data transfers for specific tags when an interrogator can seed the custody transfer process for the data packets. NASA has produced working prototypes of wearables, worn by the crew aboard the International Space Station, that reports humidity, temperature and CO2 readings. In one estimate, the battery life is on pace to last an estimated nine years. The Low-Power RFID to Collect and Store Data From Many Moving Wearable Sensors is a technology readiness level (TRL) 6 (system/subsystem prototype demonstration in a relevant environment). The innovation is now available for your company to license and develop into a commercial product. Please note that NASA does not manufacture products itself for commercial sale.

The technology utilizes photopolymer droplets (invisible to the digital radiograph) with embedded radiopaque fragments to create randomized fingerprints on battery samples. The droplets are deposited using a jig (see figure on right) that precisely positions samples. Then, at different points during battery R&D testing or use, digital radiography imaging with micron-level resolution can be performed. The high-resolution imaging required to detect dendrite formation requires images to be collected in multiple “tiles” as shown below. The randomized fingerprints uniquely identify relative positioning of these tiles, allowing rapid assembly of composite high-resolution images from multiple tiles. This same composite creation process can be used for images taken at a series of points in time during testing, and background subtraction can be applied to efficiently compare how the battery is changing over successive charge/discharge cycles to identify dendrite formation. This inspection technique is proven effective for thin-film pouch cell prototypes at NASA, and it works well at the lowest available x-ray energy level (limiting impact on the samples). The Fingerprinting for Rapid Battery Inspection technology is available for patent licensing.

With a form factor close to a deck of playing cards, the system interrogator has custom software to interface with and service a population of sensor tags at the required data rates. Each EPCglobal C1G2 sensor tag uses incident interrogator energy to charge its small integrated circuit (IC), which reads an internal memory bank, encodes identification data, and uses that information to modulate and backscatter a reply to the interrogator using reflected interrogator energy. Two tag interfaces allow the attached processor to power the reading/writing of data to the tag memory and then allows the interrogator to power the reading of the tag memory data. When neither of the two interfaces are engaged, the RFID IC is completely powered down. Reading and writing tag memory consumes relatively little power compared to the power draw of active transmitter/receiver protocols like Bluetooth, Zigbee, and Wi-Fi. Compared to passive sensing protocols, this wireless instrumentation system enables sampling of a larger population of tags without the computational burden associated with surface acoustic wave (SAW) sensing. RFID-Enabled Wireless Instrumentation technology allows the RFID interrogator to write data through the interface of a sensor tag memory bank using only interrogator power. With only minimal cost to the sensors power budget, the microcontroller unit can read that data out over the serial interface. The sensor can transmit and receive data at no effective cost to its small coin cell battery power supply. This technology is readiness level (TRL) 8 (actual system completed and "flight qualified" through test and demonstration) and the innovation is now available for your company to license. Please note that NASA does not manufacture products itself for commercial sale.

The advent of additive manufacturing makes available new and innovative integrated thermal management systems, including integrating an oscillating Heat Pipe (OHP) into the leading edge of a hypersonic vehicle for rapid dissipation of large quantities of heat. OHPs have interconnected capillary channels filled with a working fluid that forms a train of liquid plugs and vapor bubbles to facilitate rapid heat transfer. Multiple additive manufacturing techniques may be used, including powder bed fusion, binder jetting, metal material extrusion, directed energy deposit, sheet lamination, ultrasonic, and electrochemical techniques. These high performance OHPs can be made with materials such as Refractory High Entropy Alloys (RHEAs) that can withstand high temperature applications. The structure of the OHP can be integrated into the constructed leading edge. The benefits include a heat transport capacity of 10 to 100 times greater than before. Integrated OHPs avoid the bends or welds in traditional heat pipes, especially at the locations where the highest thermal stresses might cause thermal-structural failure of a leading edge. Alternating the diameters of the OHP channels alleviate start-up issues typically found in liquid metal oscillating heat pipe designs in high temperature applications by aiding in the instigation of a circulating flow due to multiple forces acting upon the working fluid.