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environment
Activated Metal Treatment System (AMTS) for Paints
Activated Metal Treatment System (AMTS) for Paints
PCBs have been shown to cause cancer in animals and to have other adverse effects on immune, reproductive, nervous, and endocrine systems. Although the production of PCBs in the United States has been banned since the late 1970s, many surfaces are still coated with PCB-laden paints. The presence of PCBs in paints adds complexity and expense for disposal. Some treatment methods (e.g., use of solvents, physical removal via scraping) are capable of removing PCBs from surfaces, but these technologies create a new waste stream that must be treated. Other methods, like incineration, can destroy the PCBs but destroy the painted structure as well, preventing reuse. To address limitations with traditional abatement methods for PCBs in paints, researchers at NASAs Kennedy Space Center (KSC) and the University of Central Florida have developed the Activated Metal Treatment System (AMTS) for Paints. This innovative technology consists of a solvent solution (e.g., ethanol, d-limonene) that contains an activated zero-valent metal. AMTS is first applied to the painted surface either using spray-on techniques or wipe-on techniques. The solution then extracts the PCBs from the paint. The extracted PCBs react with the microscale activated metal and are degraded into benign by-products. This technology can be applied without removing the paint or dismantling the painted structure. In addition, the surface can be reused following treatment.
materials and coatings
Bugs on windshield
Hydrophobic Epoxy Coating for Insect Adhesion Mitigation
This technology is a copolymeric epoxy coating that is loaded with a fluorinated aliphatic chemical species and nano- to microscale particle fillers. The coating was developed as a hydrophobic and non-wetting coating for aerodynamic surfaces to prevent accumulation of insect strike remains that can lead to natural laminar flow disruption and aerodynamic inefficiencies. The coating achieves hydrophobicity in two ways. First, the fluorinated aliphatic chemical species are hydrophobic surface modification additives that preferentially migrate to the polymer surface that is exposed to air. Secondly, the incorporation of particle fillers produces a micro-textured surface that displays excellent resistance to wetting. Combined, these two factors increase hydrophobicity and can also be used to readily generate superhydrophobic surfaces.
materials and coatings
Bug on metal
Chemical and Topographical Surface Modifications for Insect Adhesion Mitigation
The technology is a method of mitigating insect residue adhesion to various surfaces upon insect impact. The process involves topographical modification of the surface using laser ablation patterning followed by chemical modification or particulate inclusion in a polymeric matrix. Laser ablation patterning is performed by a commercially available laser system and the chemical spray deposition is composed of nanometer sized silica particles with a hydrophobic solution (e.g. heptadecafluoro-1,1,2,2-tetrahydrodecyltriethoxysilane) in an aqueous ethanol solution. Both topographic and chemical modification of the substrate is necessary to achieve the desired performance.
optics
Front image
Strobing to Mitigate Vibration for Display Legibility
The dominant frequency of the vibration that requires mitigation can be known in advance, measured in real time, or predicted with simulation algorithms. That frequency (or a lower frequency multiplier) is then used to drive the strobing rate of the illumination source. For example, if the vibration frequency is 20 Hz, one could employ a strobe rate of 1, 2, 4, 5, 10, or 20 Hz, depending on which rate the operator finds the least intrusive. The strobed illumination source can be internal or external to the display. Perceptual psychologists have long understood that strobed illumination can freeze moving objects in the visual field. This effect can be used for artistic effect or for technical applications. The present innovation is instead applicable for environments in which the human observer rather than just the viewed object undergoes vibration. Such environments include space, air, land, and sea vehicles, or on foot (e.g., walking or running on the ground or treadmills). The technology itself can be integrated into handheld and fixed display panels, head-mounted displays, and cabin illumination for viewing printed materials.
electrical and electronics
In Situ Wire Damage Detection and Rerouting System
In Situ Wire Damage Detection and Rerouting System
The tester was designed to monitor electrical faults in either online or offline modes of operation. In the online mode, wires are monitored without disturbing their normal operation. A cable can be monitored several times per second in the offline mode, and once per second in the online mode. The online cable fault locator not only detects the occurrence of a fault, but also determines the type of fault (short/open/intermittent) and the location of the fault. This enables the detection of intermittent faults that can be repaired before they become serious problems. Since intermittent faults occur mainly during operations, a built-in memory device stores all relevant fault data. This data can be displayed in real time or retrieved later so maintenance and repairs can be completed without spending countless hours attempting to pinpoint the source of the problem. Hardware and algorithms have also been developed to safely, efficiently, and autonomously transfer electrical power and data connectivity from an identified damaged/defective wire in a cable to an alternate wire path. This portion of the system consists of master and slave units that provide the diagnostic and rerouting capabilities. A test pulse generated by the master unit is sent down an active wire being monitored by the slave unit. When the slave unit detects the test pulse, it routes the pulse back to the master unit through a communication wire. When the master unit determines that a test pulse is not being returned, it designates that wire as faulty and reroutes the circuit to a spare wire.
manufacturing
Ultrasonic Stir Welding
Ultrasonic Stir Welding
Ultrasonic Stir Welding is a solid state stir welding process, meaning that the weld work piece does not melt during the welding process. The process uses a stir rod to stir the plasticized abutting surfaces of two pieces of metallic alloy that forms the weld joint. Heating is done using a specially designed induction coil. The control system has the capability to pulse the high-power ultrasonic (HPU) energy of the stir rod on and off at different rates from 1-second pulses to 60-millisecond pulses. This pulsing capability allows the stir rod to act as a mechanical device (moving and stirring plasticized nugget material) when the HPU energy is off, and allowing the energized stir rod to transfer HPU energy into the weld nugget (to reduce forces, increase stir rod life, etc.) when the HPU energy is on. The process can be used to join high-melting-temperature alloys such as titanium, Inconel, and steel.
materials and coatings
Repaired Wire Samples
Polyimide Wire Insulation Repair System
A major limitation of current aerospace wire insulation is that it tends to crack and fray as it ages and is easily damaged. Generally, it is more cost-effective to repair wire insulation than to replace a section of the wire (or bundle) itself. Current repair methods include a tape wrap repair and a heat shrink repair. These methods have a number of drawbacks: susceptibility to vibration, fluid intrusion, and other mechanical stresses. The repair patch/material can loosen or separate, exposing the bare metal conductor or opening the polyimide insulation to more damage at the interface. The technology developed by KSC is a flexible polyimide film patch (either wrap or sleeve) that is heated with a custom heating tool to melt, flow, and cure the film. The new technology results in hermetically sealed, permanent repairs that are much more flexible and less intrusive than repairs made using current practices. The repair remains flexible after application, has no limit in length or bend radius, and retains the high-temperature exposure of the original polyimide insulation. Extensive testing by NASA and NAVAIR has demonstrated that these repairs comply with industry standards for tensile strength, electrical resistivity, voltage breakdown, solvent resistance, and flammability. This system is adaptable and may also be used on larger-gauge wiring, as well as flat-ribbon wire harnesses and twisted shielded wires.
materials and coatings
Orion
Advanced Protective Coatings for Graphite-Based Nuclear Propulsion Fuel Elements
To protect the graphite (Gr)-based substrates in a nuclear systems fuel elements from hot hydrogen attacks, earlier researchers developed a method to deposit (via chemical vapor deposition) a protective niobium carbide (NbC) or zirconium carbide (ZrC) coating in the inner cooling channels of the fuel elements through which the hydrogen propellant flows. Unfortunately, the significant difference in the coefficients of thermal expansion (CTE) between the Gr-based substrate and the ZrC coating leads to debonding at intermediate temperatures, thereby exposing the substrate to hot hydrogen attack despite the NbC or ZrC coating. Innovators at Glenn have proposed a solution to this problem by introducing additional layers of compliant metallic coatings to accommodate the differences in CTE between the ZrC and the Gr-substrate,thereby potentially increasing life and durability. In this configuration,the innermost layer is composed of molybdenum carbide (Mo<sub>2</sub>C), and additional outer layers are made of molybdenum (Mo) and niobium (Nb) layers. The MoC acts as a diffusion barrier to minimize the diffusion of carbon into the refractory metal layers and the diffusion of Mo or Nb into the Gr-based substrate. The Mo layer is deposited on top of the Mo<sub>2</sub>C layer. A Nb layer is deposited on the Mo layer with the ZrC forming the outside layer of the coating. A thin Mo layer on the ZrC helps to seal the cracks on the ZrC and acts a diffusion barrier to hydrogen diffusion into the coating.The Mo and Nb layers are compliant so that differences in the thermal expansion of ZrC and other layers can be accommodated without significant debonding or cracking. They also act as additional diffusion barriers to hydrogen diffusion towards the Gr-substrate. Overall, Glenn's pioneering use of layered coatings for these components will potentially increase the durability and performance of nuclear propulsion rockets.
materials and coatings
Computer generated graphic depicts Orion's heat shield
A New Class of Strong and Flexible Carbon Fiber Reinforced Phenolic Composites
This unique approach modifies the phenolic polymer network by adding thermoplastic molecules with flexible segments such as aliphatic carbon and siloxane. The thermoplastic molecules are terminated with bifunctional groups that can directly react with the phenolic under the curing condition to form chemical bonds. Further incorporation of these segments can be facilitated by a relay reaction of a second molecular component which can bond with both the first flexible segments and the phenolic network. The selections of flexible, thermoplastic segments are based on desired properties, which include flexibility, ablative, an charring ability, heat resistance, and low catalycity. The modified phenolic is a truly molecular composite in which flexible segments are connected with the phenolic network through strong chemical bonds and are uniformly distributed among the networks. This feature renders a uniform toughening/strengthening effect without compromising the lightweight nature of the materials. The process is also feasible to scale up and amenable for manufacturing.
materials and coatings
catalyst
Low-Temperature Oxidation/ Reduction Catalysts
The low-temperature oxidation catalyst technology employs a novel catalyst formulation, termed platinized tin oxide (Pt/SnOx). The catalysts can be used on silica gel and cordierite catalyst supports, and the latest developments provide sprayable formulations for use on a range of support types and shapes. Originally developed for removal of CO, the catalyst has also proven effective for removal of formaldehyde and other lightweight hydrocarbons. NASA researchers have also extended the capability to include reduction of NOx as well as developed advanced chemistries that stabilized the catalyst for automotive catalytic converters via the engineered addition of other functional components. These catalyst formulations operate at elevated temperatures and have performed above the EPA exhaust standards for well beyond 25,000 miles. In addition, the catalyst can be used in diesel engines because of its ability to operate over an increased temperature range. For use as a gas sensor, the technology takes advantage of the exothermic nature of the catalytic reaction to detect formaldehyde, CO, or hydrocarbons, with the heat being produced proportional to the amount of analyte present.
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